Sulfur tetrachloride

Base Information Edit

Chemical Name:Sulfur tetrachloride
CAS No.:13451-08-6
Molecular Formula:Cl4S
Molecular Weight:173.878
Hs Code.:
DSSTox Substance ID:DTXSID20552819
Wikidata:Q416656
Wikipedia:Sulfur_tetrachloride
Mol file:13451-08-6.mol

Synonyms:Sulfur tetrachloride;Tetrachloro-lambda4-sulfane;13451-08-6;tetrachloro sulfide;DTXSID20552819;Q416656

Suppliers and Price of Sulfur tetrachloride

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Sulfur tetrachloride Edit

Chemical Property:

Melting Point:-30oC
Boiling Point:-15(分解)
PSA：25.30000
LogP:3.40620
XLogP3:4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:173.844532
Heavy Atom Count:5
Complexity:19.1

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:C,N
Statements: 14-34-50
Safety Statements: 26-45-61

MSDS Files:

Useful:

Canonical SMILES:S(Cl)(Cl)(Cl)Cl
Description The main use of sulfur tetrachloride is to provide fluoride to compounds with hydroxyl and carbonyl functional groups, producing corresponding fluorocarbons. This reaction is useful for making water- and oil- repelling materials for polymers, and in producing high-lubricity elastomers, with some applications in pharmaceuticals and herbicides. As a highly corrosive gas, it is difficult to handle, and this application is being phased out in favor of reactions utilizing diethylaminosulfur trifluoride. This compound however is produced using sulfur tetrachloride, which is prepared using sulfur tetrachloride.

Technology Process of Sulfur tetrachloride

There total 3 articles about Sulfur tetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 113250-69-4
chlorodifluorosulfur(IV) hexafluoroarsenate

: 13451-08-6
sulfur tetrachloride

: 12005-86-6
sodium hexafluoroarsenate

: 7783-60-0
sulfur tetrafluoride

Guidance literature:: With sodium fluoride; In liquid sulphur dioxide; {SF2Cl}(1+)*{AsF6}(1-) reacted with unhydrous NaF in liquid SO2 at -65°C for 1 h. The mixt. was warmed to -30°C and then to 25°C over 1 h.; SF4 was detected by (19)F-NMR; products not isolated.;