Phenoxydiphenylphosphine

Base Information

• Chemical Name: Phenoxydiphenylphosphine
• CAS No.: 13360-92-4
• Molecular Formula: C18H15OP
• Molecular Weight: 278.29
• Hs Code.: 2931499090
• DSSTox Substance ID: DTXSID90468332
• Nikkaji Number: J1.235.450I
• Wikidata: Q82295499
• Mol file: 13360-92-4.mol

Synonyms:Phenoxydiphenylphosphine;13360-92-4;Phenyl Diphenylphosphinite;phenoxy(diphenyl)phosphane;Phenyldiphenylphosphinite(Diphenylphosphinicacidphenylester);MFCD00046055;Phenyldiphenylphosphinite;Phosphinous acid, diphenyl-, phenyl ester;SCHEMBL195629;DTXSID90468332;UPDNYUVJHQABBS-UHFFFAOYSA-N;AKOS015855070;AS-58138;SY056329;CS-0156067;FT-0769018;P1843;F10266;A888043;J-006415

Chemical Property of Phenoxydiphenylphosphine

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.6360 to 1.6400
• Boiling Point: 391.297 °C at 760 mmHg
• Flash Point: 235.23 °C
• PSA: 22.82000
• LogP: 4.11330
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 278.086052095
• Heavy Atom Count: 20
• Complexity: 245

Purity/Quality:

98% min ^*data from raw suppliers

Phenoxydiphenylphosphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OP(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Phenoxydiphenylphosphine

There total 5 articles about Phenoxydiphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

chloro-diphenylphosphine (1079-66-9,74391-44-9) + phenol (108-95-2,27073-41-2) → phenyl diphenylphosphinite (13360-92-4)

Guidance literature:

With triethylamine; In toluene; for 18h; Heating;

DOI:10.1039/b303657j

Reference yield:

phenyldiphenylphosphinite borane complex → phenyl diphenylphosphinite (13360-92-4)

Guidance literature:

With Quinuclidine; In toluene; at 30 ℃; Kinetics;

DOI:10.1021/acs.joc.1c02729

Reference yield:

phenyl phosphorodichloridite (3426-89-9) + phenylmagnesium chloride → phenyl diphenylphosphinite (13360-92-4)

Guidance literature:

In tetrahydrofuran;

upstream raw materials:

chloro-diphenylphosphine

phenol

phenyl phosphorodichloridite

Downstream raw materials:

4-acetyl-5-methyl-2-phenoxy-2,2,3-triphenyl-2,3-dihydro-2λ⁵-[1,2]oxaphosphole

phenyl diphenylphosphinate

phenol

phenyl valerate

Refernces

• 1、 Taylor, Nicholas P.,Gonzalez, Jorge A.,Nichol, Gary S.,García-Domínguez, Andrés,Leach, Andrew G.,Lloyd-Jones, Guy C.. "A Lewis Base Nucleofugality Parameter, NFB, and Its Application in an Analysis of MIDA-Boronate Hydrolysis Kinetics". supporting information. p. 721 - 729. Retrieved 2022/01/04.
• 2、 Lal, Steven,McNally, Jayne,White, Andrew J. P.,Diez-Gonzalez, Silvia. "Novel phosphinite and phosphonite copper(I) complexes: Efficient catalysts for click azide-alkyne cycloaddition reactions". scheme or table. p. 6225 - 6232. Retrieved 2012/01/12.