CARBON MONOXIDE-17O

Base Information

• Chemical Name: CARBON MONOXIDE-17O
• CAS No.: 13311-49-4
• Molecular Formula: CO
• Molecular Weight: 29.011
• Mol file: 13311-49-4.mol

Synonyms:Carbonmonoxide (12C17O)

Chemical Property of CARBON MONOXIDE-17O

Chemical Property:

• PSA: 0.00000
• LogP: 0.00590

Purity/Quality:

99% ^*data from raw suppliers

CARBON MONOXIDE-17O 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F+,T
• Statements: 61-12-23-48/23
• Safety Statements: 53-45

MSDS Files:

Useful:

Technology Process of CARBON MONOXIDE-17O

There total 3 articles about CARBON MONOXIDE-17O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8,8-dimethoxytricyclo{3.2.1.0(2,4)}oct-2-ene + 17O-water (13968-48-4) → (17)O-carbon monoxide (13311-49-4)

Guidance literature:

With sulfuric acid; In tetrahydrofuran; suspension of org.compd., acidification with anhydrous H2SO4, addn of H2(17)O in THF, heating at 50°C for 2 h;

DOI:10.1002/hlca.19880710710

Reference yield:

bicyclo{2.2.1}hept-2-en-7-{(17)O}one (118523-84-5) → (17)O-carbon monoxide (13311-49-4)

Guidance literature:

In diethylene glycol; a soln. of ((17)O)ketone in dried diglyme was placed in a flask (cooling column connected to a gas buret through three-way valve), evacn., heating at 145°C for 12 h; 40% (17)O; collection, passing through a cooling trap (-78°C);

DOI:10.1002/hlca.19880710710

Reference yield:

graphite + dioxygen-(17)O (67321-81-7) → (17)O-carbon monoxide (13311-49-4)

Guidance literature:

In neat (no solvent); byproducts: CO2; reacting (17)O2 (74% enriched) with hot graphitic carbon at about 1700°C (resistive heating, 1E-4 Torr, 5 min); diln. of gas mixt. (CO:CO2 = 1:1 according to IR) with neon; removal of CO2 (liquid-nitrogen trap);

DOI:10.1016/0009-2614(87)80585-7

upstream raw materials:

¹⁷O-water

bicyclo{2.2.1}hept-2-en-7-{⁽¹⁷⁾O}one

dioxygen-⁽¹⁷⁾O

Downstream raw materials:

¹⁷O-water

Refernces

• 1、 Zee, R. J. van,Ferrante, R. F.,Weltner, W. Jr.. "". . p. 426 - 430. Retrieved 1987.