Propane, 2-methyl-1,1-bis(2-methylpropoxy)-

Base Information

• Chemical Name: Propane, 2-methyl-1,1-bis(2-methylpropoxy)-
• CAS No.: 13262-24-3
• Molecular Formula: C12H26 O2
• Molecular Weight: 202.337
• Hs Code.: 2909199090
• Mol file: 13262-24-3.mol

Synonyms:Isobutyraldehyde,diisobutyl acetal (7CI,8CI); Propane, 1,1-diisobutoxy-2-methyl-

Chemical Property of Propane, 2-methyl-1,1-bis(2-methylpropoxy)-

Chemical Property:

• Vapor Pressure: 0.544mmHg at 25°C
• Refractive Index: 1.42
• Boiling Point: 197°C at 760 mmHg
• Flash Point: 38.1°C
• PSA: 18.46000
• Density: 0.84g/cm³
• LogP: 3.31370

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Propane, 2-methyl-1,1-bis(2-methylpropoxy)-

There total 4 articles about Propane, 2-methyl-1,1-bis(2-methylpropoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrachloromethane (56-23-5) + 2-methyl-propan-1-ol (78-83-1) → 2-methyl-1,1-bis(2-methylpropoxy)propane (13262-24-3) + chloroform (67-66-3,8013-54-5) + hexachloroethane (67-72-1)

Guidance literature:

With iron(III) chloride hexahydrate; at 20 ℃; for 4h; UV-irradiation;

DOI:10.1134/S0023158417060052

Reference yield:

2-methyl-propan-1-ol (78-83-1) + isobutene (115-11-7,15220-85-6) → 2-methyl-1,1-bis(2-methylpropoxy)propane (13262-24-3) + isobutyl isobutanoate (97-85-8) + 1-(1,1-dimethylethoxy)-2-methylpropane (33021-02-2)

Guidance literature:

With tetrafluoroboric acid diethyl ether complex; (PCy₃)₂(CO)RuH(μ-OH)(μ-H)(PCy₃)(CO)RuH; In decane; chlorobenzene; at 100 ℃; for 24h; Schlenk technique; Autoclave; Inert atmosphere;

Reference yield:

2-methyl-propan-1-ol (78-83-1) → 3-methylbutyric acid (503-74-2) + 2-methyl-1,1-bis(2-methylpropoxy)propane (13262-24-3) + 2-methyl-1-propoxy-propane (15268-49-2) + diisobutyl ether (628-55-7) + propionaldehyde diisobutyl acetal (13002-11-4) + isobutyraldehyde (78-84-2)

Guidance literature:

With carbon monoxide; hydrogen; cobalt(II) carbonate; at 140 ℃; for 6h; under 195016 - 225018 Torr; Product distribution; Mechanism; effect of temperature, time and CO:H₂ ratio;

upstream raw materials:

2-methyl-propan-1-ol

isobutyraldehyde

isobutene

tetrachloromethane

Downstream raw materials:

isobutyl isobutanoate

2-methyl-propan-1-ol

isobutyric Acid

Refernces

• 1、 -. "CATALYST CAPABLE OF FORMING 2,5-DIMETHYLHEXENES". Paragraph 0052. . Retrieved 2015/09/23.
• 2、 Del'nik,Kagna,Katsnel'son,Rabinovich,Skop,Churakov. "PRODUCTS FORMED IN REACTIONS OF ALIPHATIC ALCOHOLS WITH CO AND H2 IN PRESENCE OF COBALT CARBONYLS.". . p. 2183 - 2188. Retrieved 2007/10/02.