Technology Process of diphenylthallium acetate
There total 13 articles about diphenylthallium acetate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
copper;
In
acetonitrile;
byproducts: TlCH3COO, CuCH3COO; Cu added to a soln. of Tl-compound, Ar bubbled through the soln. for 15min, stirred under Ar for 8 h at 45°C; Cu filtered off, soln. evapd. under vacuo, triturated with aq. trifluoroacetic acid for several times until the preciptate turned white, filtered off, dried, recrystd. (benzene/1,2-C2H4Cl2); elem. anal.;
DOI:10.1007/BF00699010
- Guidance literature:
-
In
benzene;
byproducts: thallium(I) acetate, diphenyl; soln. of organic compd. dropwise addn. to suspension of brown Tl2O3 withstirring, stirring (2 h, room temperature), acetic acid addn., stirring (3 h); next day ppt. filtration off, washing (water), drying, recrystn. (benzene-dichloromethane), Tl-acetate obtaining from aq. phase by evapn.; elem.anal.;
- Guidance literature:
-
In
benzene;
byproducts: N2, C6H5C6H5, CH3COOTl; addn. of benzene soln. of phenylhydrazine to suspn. of thallium oxide inbenzene at room temp. for 30 min under Ar, stirring for 2 h, addn. of a cetic acid, stirring for 0.5 h; filtration, washing with water, drying, elem. anal.;
DOI:10.1134/S1070363210030138
