(Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide

Base Information

• Chemical Name: (Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide
• CAS No.: 97315-84-9
• Molecular Formula: C₈H₇BrN₂O₃
• Molecular Weight: 259.059
• Mol file: 97315-84-9.mol

Synonyms:(Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide

Chemical Property of (Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide

There total 1 articles about (Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

N-methoxy-4-nitrobenzamide (1613-79-2) → (Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide (97315-84-9)

Guidance literature:

With bromine; phosphorus tribromide; In benzene; for 3h; Heating;

DOI:10.1021/jo00218a021

Reference yield: 95.0%

(Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide (97315-84-9) → (Z)-O-methyl-4-nitrobenzohydroximoyl iodide + 4-nitrobenzonitrile (619-72-7)

Guidance literature:

With sodium iodide; In sulfolane; at 95 - 97 ℃; for 96h;

DOI:10.1007/s10870-007-9257-y

Reference yield: 92.0%

(Z)-N-methoxy-4-nitrobenzenecarboximidoyl bromide (97315-84-9) + phenylacetylene (536-74-3) → (Z)-1-(4-nitrophenyl)-3-phenylprop-2-yn-1-one O-methyl oxime (1429897-14-2)

Guidance literature:

With dichloro bis(acetonitrile) palladium(II); triethylamine; triphenylphosphine; at 80 ℃; for 4h; Inert atmosphere; Glovebox;

DOI:10.1021/jo400179u

upstream raw materials:

N-methoxy-4-nitrobenzamide

Downstream raw materials:

Azetidin-1-yl-(4-nitro-phenyl)-methanone O-methyl-oxime

(Z)-O-methylpyrrolidino-p-nitrobenzamidoxime

(E)-4-aminobenzaldehyde O-methyloxime

4-Aminobenzonitrile

Refernces

• 1、 Miyata, Okiko,Koizumi, Tomoko,Asai, Hiroshi,Iba, Ryuichi,Naito, Takeaki. "Imino 1,2-Wittig rearrangement of hydroximates and its application to synthesis of cytoxazone". . p. 3893 - 3914. Retrieved 2007/10/03.