1,1,2,3,3,4,4,5,5,6,6-Undecafluorohex-1-ene

Base Information

• Chemical Name: 1,1,2,3,3,4,4,5,5,6,6-Undecafluorohex-1-ene
• CAS No.: 1767-94-8
• Molecular Formula: C6H F11
• Molecular Weight: 282.05
• Hs Code.: 2903399090
• DSSTox Substance ID: DTXSID10379850
• Mol file: 1767-94-8.mol

Synonyms:6H-Perfluorohex-1-ene;1767-94-8;1,1,2,3,3,4,4,5,5,6,6-undecafluorohex-1-ene;6h-perfluoro-1-hexene;6H-Perfluorohexene-1;SCHEMBL251092;1,1,2,3,3,4,4,5,5,6,6-undecafluoro-1-hexene;DTXSID10379850;BBL102979;MFCD00156093;STL556788;AKOS016015488;MS-20530;FT-0621151;A812209;1,1,2,3,3,4,4,5,5,6,6-undecakis(fluoranyl)hex-1-ene

Chemical Property of 1,1,2,3,3,4,4,5,5,6,6-Undecafluorohex-1-ene

Chemical Property:

• Vapor Pressure: 104mmHg at 25°C
• Refractive Index: 1.274
• Boiling Point: 78.1°Cat760mmHg
• Flash Point: 8.1°C
• PSA: 0.00000
• Density: 1.556g/cm³
• LogP: 4.23500
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 4
• Exact Mass: 281.99025981
• Heavy Atom Count: 17
• Complexity: 310

Purity/Quality:

98%Min ^*data from raw suppliers

6H-Perfluorohex-1-ene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(C(=C(F)F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 1,1,2,3,3,4,4,5,5,6,6-Undecafluorohex-1-ene

There total 1 articles about 1,1,2,3,3,4,4,5,5,6,6-Undecafluorohex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1,2-dichloro-1H,2H,6H-undecafluoro-6-iodo-hexane (812-52-2) → 1,2,11,12-Tetrachlor-docosafluor-dodecan (2263-97-0) + 1,2-dichloro-1H,2H,6H-undecafluoro-hexane (1574-47-6) + 6H-perfluoro-1-hexene (1767-94-8)

Guidance literature:

With acetic anhydride; zinc; In N,N-dimethyl-formamide; at 40 ℃;

DOI:10.1135/cccc20081719

Reference yield:

6H-perfluoro-1-hexene (1767-94-8) → 2-Chlor-2,3,3,4,4,5,5,6,6-nonafluor-capronsaeure-methylester (5923-26-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Cl₂O, Cl₂, H₂O, CCl₄

2: H₂SO₄

With tetrachloromethane; hypochlorous anhydride; sulfuric acid; water; chlorine;

upstream raw materials:

1,2-dichloro-1H,2H,6H-undecafluoro-6-iodo-hexane

Downstream raw materials:

2-Chlor-2,3,3,4,4,5,5,6,6-nonafluor-capronsaeure-methylester

Refernces