Benzyl p-toluate

Base Information

• Chemical Name: Benzyl p-toluate
• CAS No.: 1711-35-9
• Molecular Formula: C15H14 O2
• Molecular Weight: 226.275
• Mol file: 1711-35-9.mol

Synonyms:p-Toluicacid, m-tolyl ester (6CI,7CI,8CI)

Chemical Property of Benzyl p-toluate

Chemical Property:

• Melting Point: 190 °C
• Boiling Point: 196-198 °C(Press: 18 Torr)
• PSA: 26.30000
• Density: 1.101±0.06 g/cm3(Predicted)
• LogP: 3.52260

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzyl p-toluate

There total 5 articles about Benzyl p-toluate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

3-acetoxytoluene (122-46-3) + p-Toluic acid (99-94-5) → 4-methyl-benzoic acid m-tolyl ester (1711-35-9)

Guidance literature:

With phosphotungstic acid; In 5,5-dimethyl-1,3-cyclohexadiene; at 160 - 170 ℃; Reagent/catalyst;

DOI:10.2174/1570178612666150115235650

Reference yield: 74.0%

3-methyl-phenol (108-39-4) + p-Toluic acid (99-94-5) → 4-methyl-benzoic acid m-tolyl ester (1711-35-9)

Guidance literature:

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; for 16h; Heating;

DOI:10.1016/j.tetlet.2007.03.095

Reference yield:

4-methyl-benzoyl chloride (874-60-2) + 3-methyl-phenol (108-39-4) → 4-methyl-benzoic acid m-tolyl ester (1711-35-9)

Guidance literature:

With triethylamine;

DOI:10.1021/ja909818n

upstream raw materials:

3-methyl-phenol

p-Toluic acid

4-methyl-benzoyl chloride

3-acetoxytoluene

Downstream raw materials:

(2-hydroxy-4-methylphenyl)(p-tolyl)methanone

Refernces

• 1、 Xiao, Bin,Fu, Yao,Xu, Jun,Gong, Tian-Jun,Dai, Jian-Jun,Yi, Jun,Liu, Lei. "Pd(II)-catalyzed C-H activation/aryl-aryl coupling of phenol esters". supporting information; experimental part. p. 468 - 469. Retrieved 2010/03/25.