Hexafluoroacetone azine

Base Information

• Chemical Name: Hexafluoroacetone azine
• CAS No.: 1619-84-7
• Molecular Formula: C6F12 N2
• Molecular Weight: 328.06
• Hs Code.: 2928000090
• European Community (EC) Number: 630-884-9
• DSSTox Substance ID: DTXSID60408129
• Nikkaji Number: J647.673B
• Mol file: 1619-84-7.mol

Synonyms:Hexafluoroacetone azine;1619-84-7;HEXAFLUOROACETONEAZINE;1,1,1,3,3,3-hexafluoro-N-(1,1,1,3,3,3-hexafluoropropan-2-ylideneamino)propan-2-imine;1,2-bis(perfluoropropan-2-ylidene)hydrazine;Hexafluoroacetone azine, 99%;SCHEMBL3943421;DTXSID60408129;SZLJMGDRBNZIIE-UHFFFAOYSA-N;FT-0719978;J-009881;1,2-Bis(1,1,1,3,3,3-hexafluoropropane-2-ylidene)hydrazine;2-Propanone, 1,1,1,3,3,3-hexafluoro-,?2-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]hydrazone

Chemical Property of Hexafluoroacetone azine

Chemical Property:

• Vapor Pressure: 759mmHg at 25°C
• Refractive Index: n20/D 1.3(lit.)
• Boiling Point: 67-68 °C(lit.)
• Flash Point: >230 °F
• PSA: 24.72000
• Density: 1.439 g/mL at 25 °C(lit.)
• LogP: 4.03260
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 1
• Exact Mass: 327.9869860
• Heavy Atom Count: 20
• Complexity: 330

Purity/Quality:

98%Min ^*data from raw suppliers

Hexafluoroacetone azine 99% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=NN=C(C(F)(F)F)C(F)(F)F)(C(F)(F)F)C(F)(F)F

Technology Process of Hexafluoroacetone azine

There total 14 articles about Hexafluoroacetone azine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Hexafluoroacetone (684-16-2) → hexafluoroacetone azine (1619-84-7)

Guidance literature:

With hydrazine; In dichloromethane; at 20 ℃;

DOI:10.1002/kin.550260109

Reference yield: 74.0%

1,1,1,3,3,3-Hexafluoro-2-[N'-(2,2,2-trifluoro-1-hydroxy-1-trifluoromethyl-ethyl)-hydrazino]-propan-2-ol (94718-61-3) → hexafluoroacetone azine (1619-84-7)

Guidance literature:

With high percentage oleum; at 20 ℃;

Reference yield: 65.0%

Hexafluoroacetone (684-16-2) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0) → hexafluoroacetone azine (1619-84-7)

Guidance literature:

With quinoline; trichlorophosphate; In dichloromethane; with excess of (CF3)2CO, distn. in vac., stirring with POCl3 by ice cooling, standing at 20°C (4-6 h);

upstream raw materials:

2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane

N-bromo-1,1,1,3,3,3-hexafluoro-2-propanimine

(CF₃)2CN-radical

Hexafluoroacetone

Downstream raw materials:

1,5-dimethyl-1,5-diphenyl-3,3,7,7-tetrakis-trifluoromethyl-tetrahydro-pyrazolo[1,2-a]pyrazole

C₃N(CF₃)2(CF₃)2(N-2-CH₃-C₆H₄)2

1,1,1,3,3,3-hexafluoropropane

nitrogen

Refernces

• 1、 Griller,D. et al.. "-". . p. 6068 - 6070. Retrieved 1974.
• 2、 Sohn, Dieter,Sundermeyer, Wolfgang. "Reaction of Pentafluoro-2-aza-1-propene with Perfluorinated Carbenes". . p. 3334 - 3339. Retrieved 2007/10/02.