Butylsilicon

Base Information

• Chemical Name: Butylsilicon
• CAS No.: 1600-29-9
• Molecular Formula: C4H12 Si
• Molecular Weight: 88.2248
• Hs Code.: 2931900090
• European Community (EC) Number: 628-490-7
• DSSTox Substance ID: DTXSID30422857
• Mol file: 1600-29-9.mol

Synonyms:Butylsilicon;n-Butylsilane;1600-29-9;Silane, butyl- (6CI,7CI,8CI,9CI);Silane,butyl-(6ci,7ci,8ci,9ci);silapentane;DTXSID30422857;Butylsilane, >=97.0% (GC);MFCD00040079;AKOS015909375;J-009668

Chemical Property of Butylsilicon

Chemical Property:

• Vapor Pressure: 280mmHg at 25°C
• Melting Point: -56 °C
• Refractive Index: n20/D 1.392
• Boiling Point: 56.7 °C(lit.)
• Flash Point: -6℃
• PSA: 0.00000
• Density: 0.68 g/mL at 20 °C(lit.)
• LogP: 0.57020
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 85.047351822
• Heavy Atom Count: 5
• Complexity: 13.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Butylsilane ≥97.0% (GC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-33-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Si]

Technology Process of Butylsilicon

There total 9 articles about Butylsilicon which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

n-butyltrichlorosilane (7521-80-4) → n-butylsilane (1600-29-9)

Guidance literature:

With lithium aluminium tetrahydride; In various solvent(s);

Reference yield:

butyl magnesium bromide (693-04-9) → n-butylsilane (1600-29-9)

Guidance literature:

With silyl bromide; In dibutyl ether;

DOI:10.1021/ja01491a012

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + n-butyltrichlorosilane (7521-80-4) → n-butylsilane (1600-29-9)

Guidance literature:

In not given;

DOI:10.1021/ja01203a041

upstream raw materials:

n-butyl magnesium bromide

triethylsilane

n-butyltrichlorosilane

ethene

Downstream raw materials:

silacarbene

([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Bu)(Ta[PhNSiMe2CH2)2PPh])

bis(2-methylphenyl)-n-butylsilane

tris(4-methoxyphenyl)butylsilane

Refernces

• 1、 Berchier, Fabienne,Pai, Yi-Ming,Weber, William P.,Servis, Kenneth L.. "Deuterium Isotope Effects on Silicon-29 Chemical Shifts". . p. 679 - 680. Retrieved 1986.
• 2、 Moore, Darren L.,Taylor, Mark P.,Timms, Peter L.. "Reaction of Hydrogen Peroxide with Organosilanes under Chemical Vapour Deposition Conditions". . p. 2673 - 2678. Retrieved 2007/10/03.