4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate

Base Information

• Chemical Name: 4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate
• CAS No.: 32893-50-8
• Molecular Formula: C₁₀H₁₆O₄
• Molecular Weight: 200.235
• Mol file: 32893-50-8.mol

Synonyms:4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate

Chemical Property of 4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate

There total 6 articles about 4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

2,3-dihydroxy-4,4,6,6-tetramethylcyclohex-2-enone (26167-29-3) → 4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate (32893-50-8)

Guidance literature:

With iodine; potassium iodide;

Reference yield:

2-hydroxy-4,4,6,6-tetramethylcyclohex-2-enone (64637-01-0) → 4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate (32893-50-8)

Guidance literature:

Multi-step reaction with 3 steps

1: 70 percent / Br₂ / acetic acid

2: 62 percent / 1M NaOH / 110 °C

3: 57 percent / I₂, KI

With sodium hydroxide; bromine; iodine; potassium iodide; In acetic acid;

Reference yield:

3,5,5-Trimethylcyclohex-2-en-1-one (78-59-1) → 4,4,6,6-tetramethylcyclohexane-1,2,3-trione hydrate (32893-50-8)

Guidance literature:

Multi-step reaction with 6 steps

1: 1) Mg, 2) Cu(I)

2: 84.6 percent / Br₂ / acetic acid

3: 84 percent / KOH

4: 70 percent / Br₂ / acetic acid

5: 62 percent / 1M NaOH / 110 °C

6: 57 percent / I₂, KI

With potassium hydroxide; sodium hydroxide; bromine; iodine; copper; magnesium; potassium iodide; In acetic acid;

upstream raw materials:

2,3-dihydroxy-4,4,6,6-tetramethylcyclohex-2-enone

3,3,5,5-tetramethylcyclohexanone

3,5,5-Trimethylcyclohex-2-en-1-one

2-hydroxy-4,4,6,6-tetramethylcyclohex-2-enone

Downstream raw materials:

4,4,6,6-tetramethylcyclohexane-1,2,3-trione

3,3,5,5-tetramethylcyclopentane-1,2-dione

Refernces