3,6-Dibromo-9-vinylcarbazole

Base Information

• Chemical Name: 3,6-Dibromo-9-vinylcarbazole
• CAS No.: 1214-16-0
• Molecular Formula: C14H9 Br2 N
• Molecular Weight: 351.04
• Hs Code.: 2933990090
• European Community (EC) Number: 878-571-8
• DSSTox Substance ID: DTXSID30348184
• Nikkaji Number: J1.425.400E
• Wikidata: Q72465239
• Mol file: 1214-16-0.mol

Synonyms:3,6-Dibromo-9-vinylcarbazole;1214-16-0;3,6-dibromo-9-ethenylcarbazole;3,6-Dibromo-9-vinyl-9H-carbazole;SCHEMBL304192;DTXSID30348184;AMY22864;MFCD00080466;3,6-Dibromo-9-vinyl-9H-carbazole #;D5426;FT-0715256;F71978

Chemical Property of 3,6-Dibromo-9-vinylcarbazole

Chemical Property:

• Melting Point: 74-75 °C
• Boiling Point: 428.6±38.0 °C(Predicted)
• PSA: 4.93000
• Density: 1.69±0.1 g/cm3(Predicted)
• LogP: 5.42000
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 350.90813
• Heavy Atom Count: 17
• Complexity: 281

Purity/Quality:

98%Min ^*data from raw suppliers

3,6-Dibromo-9-vinylcarbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CN1C2=C(C=C(C=C2)Br)C3=C1C=CC(=C3)Br

Technology Process of 3,6-Dibromo-9-vinylcarbazole

There total 3 articles about 3,6-Dibromo-9-vinylcarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.4%

β-chloro-N-ethyl-3,6-dibromocarbazole (1147-67-7) → 3,6-dibromo-9-vinyl-9H-carbazole (1214-16-0)

Guidance literature:

With potassium hydroxide;

Reference yield: 71.0%

vinyl acetate (108-05-4,9003-20-7) + 3,6-dibromo-9H-carbazole (6825-20-3) → 3,6-dibromo-9-vinyl-9H-carbazole (1214-16-0)

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium carbonate; In toluene; at 100 ℃; for 15h; Inert atmosphere;

DOI:10.1055/s-0036-1588927

Reference yield:

→ 3,6-dibromo-9-vinyl-9H-carbazole (1214-16-0)

Guidance literature:

Carbazol IIg, Vinylbutylether;

upstream raw materials:

β-chloro-N-ethyl-3,6-dibromocarbazole

vinyl acetate

3,6-dibromo-9H-carbazole

Refernces

• 1、 Catargiu, Ana Maria,Ivan, Teofilia,Vacareanu, Loredana,Grigoras, Mircea. "Synthesis and photophysical properties of two branched carbazole-based polymers". . p. 113 - 119. Retrieved 2014/04/03.