Chlorotris(trimethylsilyl)germane

Base Information

• Chemical Name: Chlorotris(trimethylsilyl)germane
• CAS No.: 104164-55-8
• Molecular Formula: C₉H₂₇ClGeSi₃
• Molecular Weight: 327.613
• DSSTox Substance ID: DTXSID401299589
• Mol file: 104164-55-8.mol

Synonyms:Chlorotris(trimethylsilyl)germane;DTXSID401299589;104164-55-8

Chemical Property of Chlorotris(trimethylsilyl)germane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 328.0320859
• Heavy Atom Count: 14
• Complexity: 48.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)C.C[Si](C)C.C[Si](C)C.Cl[Ge]

Technology Process of Chlorotris(trimethylsilyl)germane

There total 1 articles about Chlorotris(trimethylsilyl)germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

adamontoyltris(trimethylsilyl)germane (104164-53-6) → tris(trimethylsilyl)germyl chloride (104164-55-8) + {(CH3)3Si}2Ge{C(OSi(CH3)3)C10H15} + chloroform (67-66-3,8013-54-5) + 1-Adamantanecarbonyl chloride (2094-72-6)

Guidance literature:

In tetrachloromethane; byproducts: Me3SiCl, hexachloroethane; Irradiation (UV/VIS); NMR tubes contg. the acylgermane/CCl4 sealed under vac., irradiated (two 100W Hg lamps, λ>360 nm) for up to 3h, with cooling to -15°C), soln. remained colourless; not isolated, detected by NMR-spect.;

DOI:10.1016/0022-328X(86)84028-1

upstream raw materials:

adamontoyltris(trimethylsilyl)germane

Refernces