3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine

Base Information

• Chemical Name: 3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine
• CAS No.: 127160-54-7
• Molecular Formula: C₄₃H₆₀N₂O₃
• Molecular Weight: 652.961
• Mol file: 127160-54-7.mol

Synonyms:3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine

Chemical Property of 3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine

There total 3 articles about 3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,5-di-t-butyl-4-hydroxybenzaldehyde (1620-98-0) → 3,5,3',5'-tetra-tert-butyl-4,4'-diphenoquinone (2455-14-3,74978-25-9) + 2,6-di-tert-butyl-4-cyanophenol (1988-88-1) + 2,6-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxyphenylimino)-2,5-cyclohexadien-1-one (4610-03-1) + 3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine (127160-54-7) + p-benzoquinone (106-51-4)

Guidance literature:

With ammonium hydroxide; oxygen; In propan-1-ol; at 88 ℃; for 1h; Product distribution; Mechanism; var. temp., time, aldehyde conc.;

Reference yield:

3,5-di-t-butyl-4-hydroxybenzaldehyde (1620-98-0) → 2,6-Di-tert-butyl-1,4-benzoquinone (719-22-2) + 3,5,3',5'-tetra-tert-butyl-4,4'-diphenoquinone (2455-14-3,74978-25-9) + 2,6-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxyphenylimino)-2,5-cyclohexadien-1-one (4610-03-1) + 3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine (127160-54-7) + formamide (77287-34-4,77287-35-5,60100-09-6)

Guidance literature:

With ammonium hydroxide; In ethanol; at 45 ℃; for 3h; Product distribution; other reagent, other temperature;

Reference yield:

2,6-di-tert-butyl-4-methoxymethylene-phenol (87-97-8) → 2,6-Di-tert-butyl-1,4-benzoquinone (719-22-2) + 3,5,3',5'-tetra-tert-butyl-4,4'-diphenoquinone (2455-14-3,74978-25-9) + 2,6-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxyphenylimino)-2,5-cyclohexadien-1-one (4610-03-1) + 3,5-Di-tert-butyl-N,N'-bis-(3,5-di-tert-butyl-4-oxo-cyclohexa-2,5-dienylidene)-4-oxo-cyclohexa-2,5-dienecarboxamidine (127160-54-7) + 2,6-Di-tert-butyl-4-hydroxy-4-methoxymethyl-cyclohexa-2,5-dienone + 2,6-di-tert-butyl-4-methoxymethyl-4-(3,5-di-tert-butyl-4-hydroxyphenyl)-2,5-cyclohexadien-1-one

Guidance literature:

With ammonium hydroxide; In ethanol; at 120 ℃; for 1h; Product distribution; other reagent, other temperature, other time;

upstream raw materials:

3,5-di-t-butyl-4-hydroxybenzaldehyde

2,6-di-tert-butyl-4-methoxymethylene-phenol

Refernces

• 1、 Fedulina, T. G.,Deineko, I. P.,Klindukhov, V. P.. "OXIDATION OF 3,5-DI-tert-BUTYL-4-HYDROXYBENZYL ALCOHOL AND 3,5-DI-tert-BUTYL-4-HYDROXYBENZALALDEHYDE BY OXYGEN IN AQUEOUS AMMONIUM SOLUTION". . p. 1540 - 1548. Retrieved 2007/10/02.