1,3-Bis(phenylphosphino)propane

Base Information

• Chemical Name: 1,3-Bis(phenylphosphino)propane
• CAS No.: 28240-66-6
• Molecular Formula: C15H18 P2
• Molecular Weight: 260.255
• Hs Code.: 2902909090
• DSSTox Substance ID: DTXSID60402440
• Nikkaji Number: J1.159.654A
• Mol file: 28240-66-6.mol

Synonyms:1,3-BIS(PHENYLPHOSPHINO)PROPANE;28240-66-6;phenyl(3-phenylphosphanylpropyl)phosphane;MFCD00014079;phenyl[3-(phenylphosphanyl)propyl]phosphane;1,3-bis-(Phenylphosphino)propane;1,3-diphenylphosphinopropane;1,3-diphenylphosphino propane;SCHEMBL197099;DTXSID60402440;AVNRJUHUOZDFKS-UHFFFAOYSA-N;AKOS025295051;SY038263;1,3-bis(phenylphosphino)propane, AldrichCPR;FT-0638769;F15023;A918517

Chemical Property of 1,3-Bis(phenylphosphino)propane

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 160-165°C 1mm
• Flash Point: 160-165°C/1mm
• PSA: 27.18000
• LogP: 3.38450
• Sensitive.: Air Sensitive
• Water Solubility.: Insoluble in water.
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 260.08837457
• Heavy Atom Count: 17
• Complexity: 161

Purity/Quality:

98% ^*data from raw suppliers

1,3-Bis(phenylphosphino)propane, 90-95% ^*data from reagent suppliers

Safty Information:

• Statements: 11
• Safety Statements: 9-16-33

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)PCCCPC2=CC=CC=C2

Technology Process of 1,3-Bis(phenylphosphino)propane

There total 3 articles about 1,3-Bis(phenylphosphino)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-bis-(diphenylphosphino)propane (6737-42-4) → 1,3-bis(phenylphosphano)propane (28240-66-6)

Guidance literature:

With ammonia; sodium; at -40 ℃; for 1h;

DOI:10.1002/recl.19921110402

Reference yield:

C35H42O2P2 (124791-34-0) → 1,3-bis(phenylphosphano)propane (28240-66-6)

Guidance literature:

With ammonia; sodium; at -78 ℃; for 5h;

DOI:10.1002/recl.19921110402

Reference yield:

→ 1,3-bis(phenylphosphano)propane (28240-66-6)

Guidance literature:

Kalium-phenylphosphin, 1.3-Dibrom-propan in h. Bzl. unter Stickstoff;

upstream raw materials:

1,3-bis-(diphenylphosphino)propane

C₃₅H₄₂O₂P₂

Downstream raw materials:

Trimethylen-bis-

1,3-bis(phenylphosphino)propane dioxide

C₁₅H₁₆P₂^(2-)*Mg⁽²⁺⁾

bis(hydroxy-3-propyl)phenylphosphino-1,3 propane

Refernces

• 1、 Doorn, Johannes A. van,Meijboom, Nico. "Reductive cleavage of the carbon-phosphorus bond with alkali metals. III Reactions of arylalkylphosphines". . p. 170 - 177. Retrieved 2007/10/02.