ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate

Base Information

• Chemical Name: ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate
• CAS No.: 894104-87-1
• Molecular Formula: C₄₄H₇₂O₆
• Molecular Weight: 697.052
• Mol file: 894104-87-1.mol

Synonyms:ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate

Chemical Property of ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate

There total 7 articles about ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4,5-tris(10-undecenyloxy)benzoic acid (894104-78-0) → ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate (894104-87-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: thionyl chloride / N,N-dimethylformamide / CHCl₃ / 2 h

2.1: triethylamine; magnesium chloride / tetrahydrofuran / 40 °C

2.2: tetrahydrofuran / 20 °C

2.3: 6.1 g / hydrochloric acid / tetrahydrofuran

With thionyl chloride; triethylamine; magnesium chloride; N,N-dimethyl-formamide; In tetrahydrofuran; chloroform;

DOI:10.1021/ol060488u

Reference yield:

3,4,5-tris(10-undecenyloxy)benzoic acid n-propyl ester (894104-86-0) → ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate (894104-87-1)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 78 percent / potassium hydroxide / ethanol; H₂O / 40 °C

2.1: thionyl chloride / N,N-dimethylformamide / CHCl₃ / 2 h

3.1: triethylamine; magnesium chloride / tetrahydrofuran / 40 °C

3.2: tetrahydrofuran / 20 °C

3.3: 6.1 g / hydrochloric acid / tetrahydrofuran

With potassium hydroxide; thionyl chloride; triethylamine; magnesium chloride; N,N-dimethyl-formamide; In tetrahydrofuran; ethanol; chloroform; water;

DOI:10.1021/ol060488u

Reference yield:

10-Undecen-1-ol (112-43-6) → ethyl 3,4,5-tri(10-undecenyloxy)benzoylacetate (894104-87-1)

Guidance literature:

Multi-step reaction with 6 steps

1.1: triethylamine / CH₂Cl₂ / 2 h / 20 °C

2.1: sodium iodide / acetone / 20 °C

3.1: 82 percent / potassium carbonate / acetonitrile / 48 h / Heating

4.1: 78 percent / potassium hydroxide / ethanol; H₂O / 40 °C

5.1: thionyl chloride / N,N-dimethylformamide / CHCl₃ / 2 h

6.1: triethylamine; magnesium chloride / tetrahydrofuran / 40 °C

6.2: tetrahydrofuran / 20 °C

6.3: 6.1 g / hydrochloric acid / tetrahydrofuran

With potassium hydroxide; thionyl chloride; potassium carbonate; triethylamine; sodium iodide; magnesium chloride; N,N-dimethyl-formamide; In tetrahydrofuran; ethanol; dichloromethane; chloroform; water; acetone; acetonitrile;

DOI:10.1021/ol060488u

upstream raw materials:

3,4,5-tris(10-undecenyloxy)benzoyl chloride

ethyl potassium malonate

3,4,5-tris(10-undecenyloxy)benzoic acid

3,4,5-tris(10-undecenyloxy)benzoic acid n-propyl ester

Refernces