TRIS(1-METHYLPROPYL) PHOSPHATE)

Base Information

• Chemical Name: TRIS(1-METHYLPROPYL) PHOSPHATE)
• CAS No.: 2528-45-2
• Molecular Formula: C12H27 O4 P
• Molecular Weight: 266.318
• Hs Code.: 2919900090
• Mol file: 2528-45-2.mol

Synonyms:Phosphoricacid, tri-sec-butyl ester (8CI); sec-Butyl phosphate ((C4H9O)3PO) (6CI,7CI);Tri-sec-butyl phosphate; Tris(sec-butoxy)phosphine oxide

Chemical Property of TRIS(1-METHYLPROPYL) PHOSPHATE)

Chemical Property:

• Vapor Pressure: 0.0191mmHg at 25°C
• Refractive Index: 1.427
• Boiling Point: 261.2°C at 760 mmHg
• Flash Point: 125.8°C
• PSA: 54.57000
• Density: 0.982g/cm³
• LogP: 4.53980

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(1-METHYLPROPYL) PHOSPHATE)

There total 3 articles about TRIS(1-METHYLPROPYL) PHOSPHATE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.3%

iso-butanol (78-92-2,15892-23-6) → s-butyl chloride (78-86-4,53178-20-4) + Tri-sec-butyl phosphate (2528-45-2)

Guidance literature:

With zinc(II) phosphide; oxygen; copper dichloride; at 50 ℃; under 750.06 Torr; Title compound not separated from byproducts;

Reference yield: 83.0%

iso-butanol (78-92-2,15892-23-6) → Tri-sec-butyl phosphate (2528-45-2)

Guidance literature:

With phosphorous; tetraethylammonium iodide; In water; acetonitrile; at 50 ℃; Electrolysis;

DOI:10.1016/j.jorganchem.2004.11.008

Reference yield:

→ Tri-sec-butyl phosphate (2528-45-2)

Guidance literature:

Aus Butan-2-ol u. POCl3 in Py.;

DOI:10.1016/0022-1902(60)80247-3

upstream raw materials:

iso-butanol

Downstream raw materials:

sec-Butylbenzene

2-tosyloxybutane

1-(sec-butyl)-2,4-dimethylbenzene

Refernces

• 1、 Chandrasekar, Aditi,Suresh,Sivaraman,Aswal. "Trends in small angle neutron scattering of actinide-trialkyl phosphate complexes: A molecular insight into third phase formation". . p. 92905 - 92916. Retrieved 2016/10/11.
• 2、 Dorfman,Ibraimova,Polimbetova. "Oxidative alkoxylation of zinc phosphide in alcoholic solutions of copper(II) chloride". . p. 50 - 55. Retrieved 2007/10/03.