Methylammonium nitrate

Base Information

• Chemical Name: Methylammonium nitrate
• CAS No.: 22113-87-7
• Molecular Formula: CH6N2O3
• Molecular Weight: 94.0702
• Hs Code.: 2921110090
• European Community (EC) Number: 244-787-0
• DSSTox Substance ID: DTXSID3047924
• Wikipedia: Methylammonium_nitrate
• Wikidata: Q6823957
• ChEMBL ID: CHEMBL3560728
• Mol file: 22113-87-7.mol

Synonyms:aminomethane;methylamine;methylamine bisulfite;methylamine hydride;methylamine hydrobromide;methylamine hydrochloride;methylamine hydrochloride, 14C-labeled;methylamine hydrofluoride;methylamine hydrogen cyanide;methylamine hydroiodide;methylamine ion (1-);methylamine nitrate;methylamine perchlorate;methylamine sulfate (1:1);methylamine sulfate (2:1);methylamine, 13C-labeled;methylamine, 14C-labeled;methylamine, 15N-labeled;methylamine, cesium salt;methylamine, monopotassium salt;methylamine, monosodium salt;methylammonium;methylammonium ion;monomethylamine;monomethylammonium ion

Chemical Property of Methylammonium nitrate

Chemical Property:

• Vapor Pressure: 49.8mmHg at 25°C
• Melting Point: 103oC
• Boiling Point: 83°Cat760mmHg
• Flash Point: 41°C
• PSA: 92.07000
• Density: g/cm³
• LogP: 0.45070
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 94.03784206
• Heavy Atom Count: 6
• Complexity: 26.8

Purity/Quality:

99.9% ^*data from raw suppliers

METHYLAMINE NITRATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN.[N+](=O)(O)[O-]

Technology Process of Methylammonium nitrate

There total 5 articles about Methylammonium nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2-dimethyltriazanium nitrate → methane (34557-54-5,27936-85-2) + Monomethylammonium nitrate (22113-87-7) + N,N-Dimethylhydrazine (57-14-7)

Guidance literature:

at 89.9 - 110.8 ℃; Rate constant;

DOI:10.1007/BF00952363

Reference yield:

dimethylammonium nitrate (30781-73-8) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + Monomethylammonium nitrate (22113-87-7)

Guidance literature:

With ammonium cerium(IV) nitrate; nitric acid; In water; at 54.9 ℃; Kinetics; Rate constant; other temperatures; ΔE(activ.), A, ΔH(excit.), ΔS(excit.), ΔG(excit.);

Reference yield:

methylamine (74-89-5) → Monomethylammonium nitrate (22113-87-7)

Guidance literature:

With nitric acid; In ethanol; at 10 - 20 ℃; for 1h;

DOI:10.1071/CH14161

upstream raw materials:

dimethylammonium nitrate

chloroform

dinitrogen tetraoxide

acetic acid hydrazide

Downstream raw materials:

1-methylguanidine

nicotin

1,3,5-Triazine

N-Methylformamide

Refernces

• 1、 Matsunaga, Hiroki,Katoh, Katsumi,Habu, Hiroto,Noda, Masaru,Miyake, Atsumi. "Thermal behavior of ammonium dinitramide and amine nitrate mixtures". . p. 2677 - 2685. Retrieved 2018/11/23.
• 2、 Rao, M. Anand,Sethuram, B.,Rao, T. Navaneeth. "Kinetics and Mechanism of Oxidation of Amines by Ceric Ammonium Nitrate in Nitric Acid Medium". . p. 747 - 749. Retrieved 2007/10/02.