pentacyclo[7.3.1.1~4,12~.0~2,7~.0~6,11~]tetradecan-1-ol (non-preferred name)

Base Information

• Chemical Name: pentacyclo[7.3.1.1~4,12~.0~2,7~.0~6,11~]tetradecan-1-ol (non-preferred name)
• CAS No.: 30545-19-8
• Molecular Formula: C₁₄H₂₀O
• Molecular Weight: 204.312
• Mol file: 30545-19-8.mol

Synonyms:diamantan-1-ol

Chemical Property of pentacyclo[7.3.1.1~4,12~.0~2,7~.0~6,11~]tetradecan-1-ol (non-preferred name)

Chemical Property:

• Vapor Pressure: 1.51E-05mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pentacyclo[7.3.1.1~4,12~.0~2,7~.0~6,11~]tetradecan-1-ol (non-preferred name)

There total 7 articles about pentacyclo[7.3.1.1~4,12~.0~2,7~.0~6,11~]tetradecan-1-ol (non-preferred name) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

diamantane (2292-79-7) → 4-hydroxydiamantane (30651-03-7) + MDT-14 (39646-84-9) + diamantan-1-ol (30545-19-8)

Guidance literature:

diamantane; With nitric acid; In dichloromethane; at 0 - 20 ℃; for 1h;

With sulfuric acid; In chloroform; at -15 - 0 ℃; for 1.5h; Further stages.;

DOI:10.1002/ejoc.200700378

Reference yield: 50.0%

diamantane (2292-79-7) → 4-hydroxydiamantane (30651-03-7) + diamantan-1-ol (30545-19-8)

Guidance literature:

With Bromotrichloromethane; water; molybdenum hexacarbonyl; at 140 ℃; for 12h; regioselective reaction; Inert atmosphere;

DOI:10.1134/S1070428009080041

Reference yield: 47.0%

diamantane (2292-79-7) → diamantan-1-ol (30545-19-8) + diamantane-1,4-diol (77076-31-4)

Guidance literature:

diamantane; With nitric acid; In dichloromethane; at 20 ℃; for 16h;

With water; In dichloromethane; for 2h; Further stages.; Heating;

DOI:10.1002/ejoc.200700378

upstream raw materials:

1,1,2,2-tetrachloroethylene

diamantane-3-spiro-3'-diazirine

1,1-Dichloroethylene

diamantane

Downstream raw materials:

diamantane

(3-diamantyl)acetic acid

4-diamantylacetic acid

4,9-diamantanebisacetic acid

Refernces

• 1、 Fokina, Natalie A.,Tkachenko, Boryslav A.,Merz, Anika,Serafin, Michael,Dahl, Jeremy E. P.,Carlson, Robert M. K.,Fokin, Andrey A.,Schreiner, Peter R.. "Hydroxy derivatives of diamantane, triamantane, and [121]tetramantane: Selective preparation of bis-apical derivatives". . p. 4738 - 4745. Retrieved 2007.
• 2、 Vodichka, L,Burkkhard, I.,Zakharzh, P.,Isaev, S. D.,Saichenko, S. I.,et. al.. "SYNTHESIS OF DIAMENTANE-3-SPIRO-3'-DIAZIRINE AND SOME OF ITS TRANSFORMATIONS". . p. 2350 - 2354. Retrieved 2007/10/02.