1,15-Hexadecadiene

Base Information

• Chemical Name: 1,15-Hexadecadiene
• CAS No.: 21964-51-2
• Molecular Formula: C16H30
• Molecular Weight: 222.414
• Hs Code.: 2901299090
• Mol file: 21964-51-2.mol

Synonyms:1,15-HEXADECADIENE

Chemical Property of 1,15-Hexadecadiene

Chemical Property:

• Melting Point: −14-−12 °C(lit.)
• Refractive Index: n20/D 1.447
• Boiling Point: 142-147 °C6 mm Hg(lit.)
• Flash Point: 100 °C
• PSA: 0.00000
• Density: 0.789 g/mL at 20 °C(lit.)
• LogP: 6.03960

Purity/Quality:

97% ^*data from raw suppliers

1,15-HEXADECADIENE 95.00% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,15-Hexadecadiene

There total 9 articles about 1,15-Hexadecadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

8-Bromo-1-octene (2695-48-9) → tri-oct-7-enyl-phosphane (816420-00-5) + hexadeca-1,15-diene (21964-51-2)

Guidance literature:

8-Bromo-1-octene; With magnesium; ethylene dibromide; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

With phosphorus trichloride; In tetrahydrofuran; Inert atmosphere; Cooling;

DOI:10.1515/znb-2010-0327

Reference yield: 85.0%

tri-oct-7-enyl-phosphane (816420-00-5) → hexadeca-1,15-diene (21964-51-2) + H3BP(C8H15)3 (1241849-24-0)

Guidance literature:

With dimethylsulfide borane complex; In tetrahydrofuran; at 0 ℃; for 0.166667h; chemoselective reaction; Inert atmosphere;

DOI:10.1515/znb-2010-0327

Reference yield: 78.0%

1,6-bis(p-toluenesulfonyloxy)hexane (4672-50-8) + 4-penten-1-ylmagnesium bromide (34164-50-6) → hexadeca-1,15-diene (21964-51-2)

Guidance literature:

With dilithium tetrachlorocuprate; In tetrahydrofuran; diethyl ether; at -30 ℃; for 0.25h;

DOI:10.1016/S0040-4020(01)86560-1

upstream raw materials:

1,10-dibromodecane

allyl bromide

1,6-bis(p-toluenesulfonyloxy)hexane

4-penten-1-ylmagnesium bromide

Downstream raw materials:

16-bromohexadecan-1-ol

16-bromohexadecanoic acid

1,16-hexadecanediol

Refernces

• 1、 Dennig, Alexander,Kurakin, Sara,Kuhn, Miriam,Dordic, Andela,Hall, Mélanie,Faber, Kurt. "Enzymatic Oxidative Tandem Decarboxylation of Dioic Acids to Terminal Dienes". supporting information. p. 3473 - 3477. Retrieved 2016/07/29.
• 2、 Font, Rafael,Aracil, Ignacio,Fullana, Andrés,Conesa, Juan A.. "Semivolatile and volatile compounds in combustion of polyethylene". . p. 615 - 627. Retrieved 2007/10/03.