3,5-DICHLORO-4,4'-DIHYDROXYDIPHENYLAMINE

Base Information

• Chemical Name: 3,5-DICHLORO-4,4'-DIHYDROXYDIPHENYLAMINE
• CAS No.: 2099-87-8
• Molecular Formula: C12H9 Cl2 N O2
• Molecular Weight: 270.115
• Hs Code.: 2922509090
• Mol file: 2099-87-8.mol

Synonyms:Phenol,2,6-dichloro-4,4'-iminodi- (6CI,7CI,8CI);4,4'-Dihydroxy-3,5-dichlorodiphenylamine; DPIPH2; Leuco-2,6-dichlorophenolindophenol;Reduced 2,6-dichloroindophenol; Reduced 2,6-dichlorophenolindophenol

Chemical Property of 3,5-DICHLORO-4,4'-DIHYDROXYDIPHENYLAMINE

Chemical Property:

• PSA: 52.49000
• LogP: 4.22120

Purity/Quality:

99%min ^*data from raw suppliers

Leuco-2,6-dichlorophenolindophenol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Leuco-2,6-dichlorophenolindophenol is the reduced form of DCIP and has been used to measure photocatalytic oxidation.

Technology Process of 3,5-DICHLORO-4,4'-DIHYDROXYDIPHENYLAMINE

There total 7 articles about 3,5-DICHLORO-4,4'-DIHYDROXYDIPHENYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2,6-Dichlorophenolindophenol (956-48-9) → 2,6-Dichloroindophenol reduced (2099-87-8)

Guidance literature:

With [Ni^IICl(N,N’-dimethyl-3,7-diazanonane-1,9-dithiolato)Ir^IIICl(η⁵-C₅Me₅)]; hydrogen; In water; at 60 ℃; for 2h; under 6000.6 Torr; pH=4 - 10; Reagent/catalyst; pH-value; Temperature; Pressure; Catalytic behavior; Glovebox; Schlenk technique;

DOI:10.1002/anie.201704864

Reference yield:

2,6-Dichlorophenolindophenol (956-48-9) + ascorbic acid (50-81-7,98966-42-8) → 2,6-Dichloroindophenol reduced (2099-87-8) + L-dehydroascorbic acid (490-83-5)

Guidance literature:

With hydrogenchloride; In water; pH=2 - 7; Time; Kinetics; aq. acetate buffer;

DOI:10.1021/ac200842e

Reference yield:

dichlorophenolindophenol (537-14-4) + 2-propanethiol (75-33-2) → diisopropyl sulfide (4253-89-8) + 2,6-Dichloroindophenol reduced (2099-87-8)

Guidance literature:

With sodium hydroxide; In methanol; water; at 30 ℃; Kinetics; Mechanism; Thermodynamic data; ΔH*, ΔS*, SDF*; variation of the conc. of reaction partners, and of the temperature;

upstream raw materials:

2,6-Dichlorophenolindophenol

1-thiopropane

dichlorophenolindophenol

2-propanethiol

Refernces

• 1、 Ogo, Seiji,Mori, Yuki,Ando, Tatsuya,Matsumoto, Takahiro,Yatabe, Takeshi,Yoon, Ki-Seok,Hayashi, Hideki,Asano, Masashi. "One Model, Two Enzymes: Activation of Hydrogen and Carbon Monoxide". . p. 9723 - 9726. Retrieved 2017.
• 2、 Hajipour, Gholamhossein,Schowen, K. Barbara,Schowen, Richard L.. "The linkage of catalysis and regulation in enzyme action: Oxidative diversion in the hysteretically regulated yeast pyruvate decarboxylase". . p. 887 - 894. Retrieved 1999.
• 3、 Peters, Kevin C.,Comi, Troy J.,Perry, Richard H.. "Multistage Reactive Transmission-Mode Desorption Electrospray Ionization Mass Spectrometry". . p. 1494 - 1501. Retrieved 2015/08/18.