N-[(9E)-2-nitro-9H-fluoren-9-ylidene]aniline

Base Information

• Chemical Name: N-[(9E)-2-nitro-9H-fluoren-9-ylidene]aniline
• CAS No.: 75158-95-1
• Molecular Formula: C19H12 N2 O2
• Molecular Weight: 300.316
• Mol file: 75158-95-1.mol

Synonyms:Aniline,N-2-nitrofluoren-9-ylidene- (6CI); NSC 12330

Chemical Property of N-[(9E)-2-nitro-9H-fluoren-9-ylidene]aniline

Chemical Property:

• Vapor Pressure: 1.05E-08mmHg at 25°C
• Boiling Point: 474.3°Cat760mmHg
• Flash Point: 240.6°C
• Density: 1.28g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-[(9E)-2-nitro-9H-fluoren-9-ylidene]aniline

There total 8 articles about N-[(9E)-2-nitro-9H-fluoren-9-ylidene]aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

C33H25N3O4S2 (75158-94-0) → 2-nitro-9-(N-phenyl)-iminofluorene (75158-95-1)

Guidance literature:

In 1,2-dichloro-ethane; Ambient temperature;

DOI:10.1246/bcsj.53.1023

Reference yield: 73.0%

2-nitro-9H-fluoren-9-one (3096-52-4) + aniline (62-53-3) → 2-nitro-9-(N-phenyl)-iminofluorene (75158-95-1)

Guidance literature:

With aluminium trichloride; In toluene; for 3h; Heating;

Reference yield:

C19H13IN2O2 → C19H12N2O2 (75158-95-1)

Guidance literature:

With cesium pivalate; palladium diacetate; bis-diphenylphosphinomethane; In N,N-dimethyl-formamide; at 100 ℃; for 12h;

DOI:10.1021/ja070657l

upstream raw materials:

2-nitro-9H-fluoren-9-one

aniline

C₃₃H₂₅N₃O₄S₂

S-(2-nitro-fluoren-9-ylidene)-N-(toluene-4-sulfonyl)-sulfimide

Downstream raw materials:

(2-Nitro-9-phenylamino-9H-fluoren-9-yl)-phosphonic acid

(2-Nitro-9-phenylamino-9H-fluoren-9-yl)-phosphonic acid diethyl ester

Refernces

• 1、 Gancarz, R.,Wieczorek, J. S.. "Synthesis of Phosphonic Analogues of Morphactines". . p. 213 - 222. Retrieved 2007/10/02.