allyldimethyl[(E)-2-phenylethen-1-yl]silane

Base Information Edit

Chemical Name:allyldimethyl[(E)-2-phenylethen-1-yl]silane
CAS No.:135068-04-1
Molecular Formula:C₁₃H₁₈Si
Molecular Weight:202.371
Hs Code.:
Mol file:135068-04-1.mol

Synonyms:allyldimethyl[(E)-2-phenylethen-1-yl]silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of allyldimethyl[(E)-2-phenylethen-1-yl]silane Edit

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Technology Process of allyldimethyl[(E)-2-phenylethen-1-yl]silane

There total 5 articles about allyldimethyl[(E)-2-phenylethen-1-yl]silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: allyldimethyl(phenylethynyl)silane

: 135068-04-1
allyldimethyl[(E)-2-phenylethen-1-yl]silane

Guidance literature:: With diisobutylaluminium hydride; In hexane; at 0 - 55 ℃; for 0.75h; stereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201306882

Reference yield: 6.0%

: 2295-12-7
1,1-dimethylsilacyclobutane

: 536-74-3
phenylacetylene

: 135068-04-1
allyldimethyl[(E)-2-phenylethen-1-yl]silane

: 57060-75-0
1,1-Dimethyl-3-phenyl-1-sila-2-cyclohexene

Guidance literature:: bis-triphenylphosphine-palladium(II) chloride; In benzene; for 2h; Heating;
DOI:10.1246/bcsj.64.1461

Reference yield:

: 536-74-3
phenylacetylene

: 135068-04-1
allyldimethyl[(E)-2-phenylethen-1-yl]silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / hexane / 0.75 h / 0 - 55 °C / Inert atmosphere

With n-butyllithium; diisobutylaluminium hydride; In tetrahydrofuran; hexane;
DOI:10.1002/anie.201306882