[2-[2-Bis(3,5-ditert-butylphenyl)phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(3,5-ditert-butylphenyl)phosphane

Base Information

• Chemical Name: [2-[2-Bis(3,5-ditert-butylphenyl)phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(3,5-ditert-butylphenyl)phosphane
• CAS No.: 192138-05-9
• Molecular Formula: C₇₀H₉₆O₂P₂
• Molecular Weight: 1031.48
• Hs Code.: 29319090
• European Community (EC) Number: 811-688-4,811-690-5
• Nikkaji Number: J1.200.253J,J760.038K
• Mol file: 192138-05-9.mol

Synonyms:167709-31-1;192138-05-9;[2-[2-bis(3,5-ditert-butylphenyl)phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(3,5-ditert-butylphenyl)phosphane;(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-3,5-t-Bu-MeOBIPHEP;(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine];(S)-(6,6'-DIMETHOXYBIPHENYL-2,2'-DIYL)BIS[BIS(3,5-DI-TERT-BUTYLPHENYL)PHOSPHINE];Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)phenyl]-;(S)-(-)-2,2/'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6/'-dimethoxy-1,1/'-biphenyl,min.97per cent;MFCD09753001;Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)phenyl]-;SCHEMBL1985478;PBYRAYONARLAQJ-UHFFFAOYSA-N;E76887;E76888;J-010389;J-012418;2,2'-Bis[bis(3,5-di-tert-butylphenyl)phosphino]-6,6'-dimethoxybiphenyl;(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(bis(3,5-di-tert-butylphenyl)phosphane);(aR)-2,2'-Dimethoxy-6,6'-bis[bis(3,5-di-tert-butylphenyl)phosphino]biphenyl;(R)-(+)-2,2/'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6/'-dimethoxy-1,1/'-biphenyl,min.97per cent;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine], >=97%, optical purity ee: >=99%;(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine], >=97%, optical purity ee: >=99%;2033140-76-8

Chemical Property of [2-[2-Bis(3,5-ditert-butylphenyl)phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(3,5-ditert-butylphenyl)phosphane

Chemical Property:

• Boiling Point: 856.5±65.0 °C(Predicted)
• PSA: 27.18000
• LogP: 7.03310
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• XLogP3: 22.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 17
• Exact Mass: 1030.68855630
• Heavy Atom Count: 74
• Complexity: 1430

Purity/Quality:

98%,99%, ^*data from raw suppliers

(R)-(+)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)C1=CC(=CC(=C1)P(C2=CC=CC(=C2C3=C(C=CC=C3P(C4=CC(=CC(=C4)C(C)(C)C)C(C)(C)C)C5=CC(=CC(=C5)C(C)(C)C)C(C)(C)C)OC)OC)C6=CC(=CC(=C6)C(C)(C)C)C(C)(C)C)C(C)(C)C
• Uses: (R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] can be used as a ligand to prepare:1,2-Dihydropyridines through Rh-catalyzed cycloaddition of diynes to sulfonimines.Enantiorich disubstituted γ-lactams via intramolecular allylic alkylation reaction using Pd catalyst.A Ru-metal complex, which acts as a hydrogenation catalyst applicable in the synthesis of an organic building block (S)-3-fluoromethyl-γ-butyrolactone.