p-methoxythiobenzoyl isocyanate

Base Information

• Chemical Name: p-methoxythiobenzoyl isocyanate
• CAS No.: 3553-62-6
• Molecular Formula: C₉H₇NO₂S
• Molecular Weight: 193.226
• Mol file: 3553-62-6.mol

Synonyms:p-methoxythiobenzoyl isocyanate

Chemical Property of p-methoxythiobenzoyl isocyanate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-methoxythiobenzoyl isocyanate

There total 3 articles about p-methoxythiobenzoyl isocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5-p-methoxyphenyl-1,2,4-dithiazole-3-one (7047-13-4) + triphenyl phosphite (101-02-0) → O,O,O-triphenyl phosphorothioate (597-82-0) + p-methoxythiobenzoyl isocyanate (3553-62-6)

Guidance literature:

In acetonitrile; at 25 ℃; Solvent; Kinetics;

DOI:10.1039/c2ob26460a

Reference yield:

2-para-methoxyphenyl-1,3-thiazolidine-4,5-dione (3553-57-9) → p-methoxythiobenzoyl isocyanate (3553-62-6)

Guidance literature:

In toluene; for 0.0833333h; Heating;

DOI:10.1016/j.tet.2007.11.107

Reference yield:

→ p-methoxythiobenzoyl isocyanate (3553-62-6)

Guidance literature:

A) /BRN= 75526/, therm.Zers. durch Sublimation o. Dest. im Vak.;

upstream raw materials:

2-para-methoxyphenyl-1,3-thiazolidine-4,5-dione

5-p-methoxyphenyl-1,2,4-dithiazole-3-one

triphenyl phosphite

Downstream raw materials:

5-(4-Methoxy-phenyl)-[1,2,4]thiadiazol-3-ol

2,6-bis-(4-methoxy-phenyl)-[1,3,5]thiadiazin-4-one

Refernces

• 1、 Morita, Mikio,Hari, Yoshiyuki,Iguchi, Tomoe,Aoyama, Toyohiko. "Facile synthesis of 2-azaazulenes from thiobenzoyl isocyanates using trimethylsilyldiazomethane". . p. 1753 - 1758. Retrieved 2008/09/17.