Technology Process of (η-5-cyclopentadienyl)dicarbony((η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium-P)manganese
There total 1 articles about (η-5-cyclopentadienyl)dicarbony((η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium-P)manganese which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
THF;
In
tetrahydrofuran;
Irradiation (UV/VIS); Mn complex photolysing in THF for 4 h at 15°C with stirring under Ar, adding to Ti complex, stirring overnight, evapg., washing with hexane, dissolving in CH2Cl2, filtering through Celite, concg., hexane adding, after 36-72 h red crystals sepg.; purified by recrystn. from CH2Cl2/hexane; identified by elem. anal., IRand NMR spectra;
DOI:10.1021/ja00350a024
