2-Phenyl-naphtho<1,2-d>thiazol

Base Information

• Chemical Name: 2-Phenyl-naphtho<1,2-d>thiazol
• CAS No.: 72142-85-9
• Molecular Formula: C₁₇H₁₁NS
• Molecular Weight: 261.347
• Mol file: 72142-85-9.mol

Synonyms:2-Phenyl-naphtho<1,2-d>thiazol

Chemical Property of 2-Phenyl-naphtho<1,2-d>thiazol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Phenyl-naphtho<1,2-d>thiazol

There total 14 articles about 2-Phenyl-naphtho<1,2-d>thiazol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-(naphthalen-1-yl)benzothioamide (96963-47-2) → 2-Phenyl-naphtho<1,2-d>thiazol (72142-85-9)

Guidance literature:

With dmap; Co^III(dimethylglyoximate)₂(4-NMe₂-C₅H₄N)Cl; [Ni(2,2'-bipyridine)₃][PF₆]₂; sodium glycinate; In acetonitrile; at 20 ℃; for 12h; Inert atmosphere; Irradiation; Schlenk technique;

DOI:10.1021/jacs.5b05665

Reference yield: 92.0%

(E)-N-(naphthalen-1-yl)-1-phenylmethanimine (78569-36-5) → 2-Phenyl-naphtho<1,2-d>thiazol (72142-85-9)

Guidance literature:

With oxygen; sulfur; potassium iodide; In acetonitrile; at 20 - 120 ℃; for 12h; Sealed tube; Green chemistry;

DOI:10.1016/j.tet.2021.132624

Reference yield: 89.0%

1-amino-naphthalene (134-32-7) + benzylamine (100-46-9) → 2-Phenyl-naphtho<1,2-d>thiazol (72142-85-9)

Guidance literature:

With oxygen; sulfur; potassium iodide; In acetonitrile; at 20 - 120 ℃; for 12h; Reagent/catalyst; Solvent; Mechanism; Sealed tube; Green chemistry;

DOI:10.1016/j.tet.2021.132624

upstream raw materials:

N-1-naphthalenyl-benzamide

N-(naphthalen-1-yl)benzothioamide

1-amino-naphthalene

toluene

Downstream raw materials:

1-aminonaphthalene-2-thiol

Refernces

• 1、 Bai, Jin,Yan, Sijia,Zhang, Zhuxia,Guo, Zhen,Zhou, Cong-Ying. "Visible-Light Carbon Nitride-Catalyzed Aerobic Cyclization of Thiobenzanilides under Ambient Air Conditions". . p. 4843 - 4848. Retrieved 2021/06/28.
• 2、 Bouchet, Lydia M.,Heredia, Adrián A.,Argüello, Juan E.,Schmidt, Luciana C.. "Riboflavin as Photoredox Catalyst in the Cyclization of Thiobenzanilides: Synthesis of 2-Substituted Benzothiazoles". supporting information. p. 610 - 614. Retrieved 2020/01/31.