2-isopropyl-9-phenyl-[1,10]phenanthroline

Base Information

• Chemical Name: 2-isopropyl-9-phenyl-[1,10]phenanthroline
• CAS No.: 1263175-14-9
• Molecular Formula: C₂₁H₁₈N₂
• Molecular Weight: 298.387
• Mol file: 1263175-14-9.mol

Synonyms:2-isopropyl-9-phenyl-[1,10]phenanthroline

Chemical Property of 2-isopropyl-9-phenyl-[1,10]phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2-isopropyl-9-phenyl-[1,10]phenanthroline

There total 4 articles about 2-isopropyl-9-phenyl-[1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2-isopropyl-[1,10]phenanthroline + phenyllithium (591-51-5) → 2-isopropyl-9-phenyl-[1,10]phenanthroline (1263175-14-9)

Guidance literature:

2-isopropyl-[1,10]phenanthroline; phenyllithium; In toluene; at 0 - 20 ℃; for 18h; Inert atmosphere;

With manganese(IV) oxide; In dichloromethane; water; for 6h; Inert atmosphere;

DOI:10.1002/chem.202001209

Reference yield: 87.0%

2-phenyl-1,10-phananthroline (109559-47-9) + isopropyllithium (1888-75-1) → 2-isopropyl-9-phenyl-[1,10]phenanthroline (1263175-14-9)

Guidance literature:

2-phenyl-1,10-phananthroline; isopropyllithium; In toluene; pentane; at -35 - 0 ℃; for 0.583333h; Inert atmosphere; Glovebox; Schlenk technique;

With manganese(IV) oxide; In dichloromethane; for 12h; Inert atmosphere; Glovebox; Schlenk technique;

Reference yield: 50.0%

ethyl vinyl ether (109-92-2,25104-37-4) + isovaleraldehyde (590-86-3) + 2-phenylquinolin-8-ylamine (116529-78-3) → 2-isopropyl-9-phenyl-[1,10]phenanthroline (1263175-14-9)

Guidance literature:

ethyl vinyl ether; isovaleraldehyde; 2-phenylquinolin-8-ylamine; In 2,2,2-trifluoroethanol; at 20 ℃;

With hydrogenchloride; oxygen; In water; acetonitrile; for 16h; under 760.051 Torr;

DOI:10.1039/c0ob00496k

upstream raw materials:

ethyl vinyl ether

isovaleraldehyde

2-phenylquinolin-8-ylamine

phenyllithium

Refernces

• 1、 -. "HAFNIUM COMPOUND AND CATALYST COMPOSITION COMPRISING THE SAME". Paragraph 0156; 0185; 0188-189. . Retrieved 2021/01/09.