(Z)-α-Nitrostilbene

Base Information

• Chemical Name: (Z)-α-Nitrostilbene
• CAS No.: 15341-31-8
• Molecular Formula: C₁₄H₁₁NO₂
• Molecular Weight: 225.247
• Mol file: 15341-31-8.mol

Synonyms:((Z)-(1-nitroethene-1,2-diyl)dibenzene)

Chemical Property of (Z)-α-Nitrostilbene

Chemical Property:

• Storage Temp.: room temp
• Solubility.: DMSO: soluble20mg/mL, clear

Purity/Quality:

CID 2818500 ≥98% (HPLC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-51

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-α-Nitrostilbene

There total 47 articles about (Z)-α-Nitrostilbene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(E)-1,2-diphenyl-ethene (103-30-0) + Nitrogen dioxide (10102-44-0) → α-nitro-stilbene (15341-31-8,18315-83-8,82864-83-3,1215-07-2) + benzaldehyde (100-52-7) + benzil (134-81-6) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

In tetrachloromethane; react. at 25°C; products identified by g.c./m.s.;

DOI:10.1039/c39890001027

Reference yield: 57.0%

(E)-1,2-diphenyl-ethene (103-30-0) → α-nitro-stilbene (15341-31-8,18315-83-8,82864-83-3,1215-07-2)

Guidance literature:

With silver nitrate; acetyl chloride; In acetonitrile; at 0 - 65 ℃; for 1h;

DOI:10.1021/jo200475h

Reference yield: 39.0%

cis-stilben (645-49-8) + Nitrogen dioxide (10102-44-0) → α-nitro-stilbene (15341-31-8,18315-83-8,82864-83-3,1215-07-2) + benzaldehyde (100-52-7) + benzil (134-81-6)

Guidance literature:

In tetrachloromethane; react. at 25°C; products identified by g.c./m.s.;

DOI:10.1039/c39890001027

upstream raw materials:

(E)-(1-nitroethene-1,2-diyl)dibenzene

meso-1,2-dinitro-1,2-diphenylethane

(+/-)-1,2-dinitro-1,2-diphenylethane

C₁₆H₁₆NO₂S^(1-)

Downstream raw materials:

methyl 2-methoxycarbonyl-3,4-diphenyl-4-nitrobutanoate

cis-1,2-dinitrostilbene

1,4,5-triphenyl-1H-1,2,3-triazole

2,3-diphenyl-1H-indole

Refernces

• 1、 Jana, Sourav,Chakraborty, Amrita,Shirinian, Valerii Z.,Hajra, Alakananda. "Synthesis of Benzo[4,5]imidazo[2,1-b]thiazole by Copper(II)-Catalyzed Thioamination of Nitroalkene with 1H-Benzo[d]imidazole-2-thiol". supporting information. p. 2402 - 2408. Retrieved 2018/05/08.
• 2、 -. "PREPARATION OF ALDEHYDES AND KETONES FROM ALKENES USING POLYOXOMETALATE CATALYSTS AND NITROGEN OXIDES". Paragraph 0116. . Retrieved 2017/03/21.