capsidiol 3-phenylthionocarbonate

Base Information

• Chemical Name: capsidiol 3-phenylthionocarbonate
• CAS No.: 799813-16-4
• Molecular Formula: C₂₂H₂₈O₃S
• Molecular Weight: 372.529
• Mol file: 799813-16-4.mol

Synonyms:capsidiol 3-phenylthionocarbonate

Chemical Property of capsidiol 3-phenylthionocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of capsidiol 3-phenylthionocarbonate

There total 1 articles about capsidiol 3-phenylthionocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

capsidiol (37208-05-2) + phenylcarbonochloridothioate (1005-56-7) → capsidiol 3-phenylthionocarbonate (799813-16-4)

Guidance literature:

With pyridine; In dichloromethane; at 20 ℃; for 8h;

DOI:10.1021/jo049058c

Reference yield:

capsidiol 3-phenylthionocarbonate (799813-16-4) → epiaristolochen-1-one tosylhydrazone

Guidance literature:

Multi-step reaction with 3 steps

1: 81 percent / (Bu₃Sn)2O; AIBN; PMHS / benzene / 5 h / Heating

2: 88 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / -78 - 20 °C

3: ethanol / 1 h / Heating

With oxalyl dichloride; 2,2'-azobis(isobutyronitrile); dimethyl sulfoxide; triethylamine; bis(tri-n-butyltin)oxide; In ethanol; dichloromethane; benzene;

DOI:10.1021/jo049058c

Reference yield:

capsidiol 3-phenylthionocarbonate (799813-16-4) → epiaristolochen-1-one (800385-98-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 81 percent / (Bu₃Sn)2O; AIBN; PMHS / benzene / 5 h / Heating

2: 88 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / -78 - 20 °C

With oxalyl dichloride; 2,2'-azobis(isobutyronitrile); dimethyl sulfoxide; triethylamine; bis(tri-n-butyltin)oxide; In dichloromethane; benzene;

DOI:10.1021/jo049058c

upstream raw materials:

capsidiol

phenylcarbonochloridothioate

Downstream raw materials:

epiaristolochen-1-one

Refernces