bis(pentafluorophenyl)methyl chloride

Base Information

• Chemical Name: bis(pentafluorophenyl)methyl chloride
• CAS No.: 5736-48-1
• Molecular Formula: C₁₃HClF₁₀
• Molecular Weight: 382.588
• Mol file: 5736-48-1.mol

Synonyms:bis(pentafluorophenyl)methyl chloride

Chemical Property of bis(pentafluorophenyl)methyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(pentafluorophenyl)methyl chloride

There total 2 articles about bis(pentafluorophenyl)methyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.3%

decafluorobenzhydrol (1766-76-3) → bis(pentafluorophenyl)methyl chloride (5736-48-1)

Guidance literature:

With pyridine; thionyl chloride; for 2h; Heating;

DOI:10.1021/jo00077a040

Reference yield:

1-chloro-2,3,4,5,6-pentafluorobenzene (344-07-0) → bis(pentafluorophenyl)methyl chloride (5736-48-1)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) Mg, (ii) /BRN= 906769/

2: PCl₅ / CCl₄

With phosphorus pentachloride; In tetrachloromethane;

Reference yield: 63.0%

bis(pentafluorophenyl)methyl chloride (5736-48-1) + boron trifluoride diethyl etherate (109-63-7) → tris[bis(pentafluorophenyl)methyl]borane

Guidance literature:

With iodine; magnesium; In diethyl ether; for 12h; Inert atmosphere; Schlenk technique; Glovebox; Reflux;

DOI:10.1039/c5dt00821b

upstream raw materials:

decafluorobenzhydrol

1-chloro-2,3,4,5,6-pentafluorobenzene

Downstream raw materials:

1,1,2,2-tetrakis-(pentafluoro phenyl) ethane

Tris(pentafluorophenyl)methane

3,5-Dichlor-2,4,6-trifluorphenyl-bispentafluorphenylmethan

bis(pentafluorophenyl)methane

Refernces

• 1、 Tomioka, Hideo,Mizutani, Kenzoh,Matsumoto, Kenji,Hirai, Katsuyuki. "Generation, Reactions, Direct Observation, and Kinetics of Decafluorodiphenylcarbene". . p. 7128 - 7134. Retrieved 2007/10/02.