butyl phenyl tolylphosphinate

Base Information

• Chemical Name: butyl phenyl tolylphosphinate
• CAS No.: 86662-16-0
• Molecular Formula: C₁₇H₂₁O₂P
• Molecular Weight: 288.326
• Mol file: 86662-16-0.mol

Synonyms:butyl phenyl tolylphosphinate

Chemical Property of butyl phenyl tolylphosphinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of butyl phenyl tolylphosphinate

There total 2 articles about butyl phenyl tolylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

2-methylphenyl bromide (95-46-5) + butyl phenylphosphinate (6172-81-2) → butyl phenyl tolylphosphinate (86662-16-0)

Guidance literature:

With triethylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; at 120 ℃; for 2h;

DOI:10.1055/s-1983-30341

Reference yield:

butyl phenylphosphinate (6172-81-2) + toluene (108-88-3,15644-74-3,16713-13-6) → butyl phenyl tolylphosphinate (41044-92-2) + butyl phenyl tolylphosphinate + butyl phenyl tolylphosphinate (86662-16-0)

Guidance literature:

With manganese(IV) oxide; sodium acetate; manganese(II) acetate; acetic acid; at 70 ℃; for 4h; Overall yield = 70 %; Overall yield = 202 mg; Inert atmosphere;

DOI:10.1002/chem.201404507

upstream raw materials:

2-methylphenyl bromide

butyl phenylphosphinate

toluene

Refernces

• 1、 Xu, Yuanyao,Li, Zhong,Xia, Jiazhi,Guo, Huiju,Huang, Yaozeng. "Palladium-Catalysed Synthesis of Unsymmetrical Alkyl Aryl-phenylphosphinates". . p. 377 - 378. Retrieved 2007/10/02.