1-(4-nitro-phenyl)-ethanone; radical anion

Base Information

• Chemical Name: 1-(4-nitro-phenyl)-ethanone; radical anion
• CAS No.: 34512-32-8
• Molecular Formula: C₈H₇NO₃
• Molecular Weight: 165.148
• Mol file: 34512-32-8.mol

Synonyms:1-(4-nitro-phenyl)-ethanone; radical anion

Chemical Property of 1-(4-nitro-phenyl)-ethanone; radical anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(4-nitro-phenyl)-ethanone; radical anion

There total 8 articles about 1-(4-nitro-phenyl)-ethanone; radical anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nitrobenzene radical anion (98-95-3,12169-65-2) + (4-nitrophenyl)ethanone (100-19-6) → nitrobenzene (98-95-3,26969-40-4) + 1-(4-nitro-phenyl)-ethanone; radical anion (34512-32-8)

Guidance literature:

at 250 ℃; Thermodynamic data; ΔS⁰, ΔH⁰, ΔG⁰;

DOI:10.1021/ja00278a014

Reference yield:

(4-nitrophenyl)ethanone (100-19-6) + trimethylamine (75-50-3) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + dimethyl amine (124-40-3) + 1-(4-nitro-phenyl)-ethanone; radical anion (34512-32-8)

Guidance literature:

With water; dinitrogen monoxide; Rate constant; Product distribution; Irradiation; influence of phosphate buffer (pH=7) on rate; dependence of rate on concentration of PNAP; dependence of PNAP(-.) yield on pH;

Reference yield:

2-hydroxy-2-propyl radical (5131-95-3) + (4-nitrophenyl)ethanone (100-19-6) → acetone (67-64-1) + 1-(4-nitro-phenyl)-ethanone; radical anion (34512-32-8)

Guidance literature:

In water; at 20 ℃; Rate constant;

DOI:10.1021/ja00334a015

upstream raw materials:

ethanol radical

(4-nitrophenyl)ethanone

2-hydroxy-2-propyl radical

carbon dioxide anion radical

Refernces

• 1、 Chowdhury, Swapan,Kebarle, Paul. "Electron Affinities of Di- and Tetracyanoethylene and Cyanobenzenes Based on Measurements of Gas-Phase Electron-Transfer Equilibria". . p. 5453 - 5459. Retrieved 2007/10/02.
• 2、 Jagannadham, V.,Steenken, S.. "One-Electron Reduction of Nitrobenzenes by α-Hydroxyalkyl Radicals via Addition/Elimination. An Example of an Organic Inner-Sphere Electron-Transfer Reaction". . p. 6542 - 6551. Retrieved 2007/10/02.