C₁₄H₁₄BrN

Base Information

• Chemical Name: C₁₄H₁₄BrN
• CAS No.: 1632199-11-1
• Molecular Formula: C₁₄H₁₄BrN
• Molecular Weight: 276.176
• Mol file: 1632199-11-1.mol

Synonyms:C₁₄H₁₄BrN

Chemical Property of C₁₄H₁₄BrN

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₁₄H₁₄BrN

There total 1 articles about C₁₄H₁₄BrN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5-bromoquinoline (4964-71-0) → C14H14BrN (1632199-11-1)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 3-chloro-benzenecarboperoxoic acid / ethyl acetate / 2 h / 20 °C

2.1: trichlorophosphate / chloroform / 2 h / 70 °C

3.1: magnesium; iodine / tetrahydrofuran / 1.5 h / 0 °C / Inert atmosphere; Reflux

3.2: 0.25 h / 0 °C / Inert atmosphere

3.3: 18 h / 70 °C / Inert atmosphere

With iodine; magnesium; 3-chloro-benzenecarboperoxoic acid; trichlorophosphate; In tetrahydrofuran; chloroform; ethyl acetate;

DOI:10.1055/s-0033-1341072

Reference yield: 100.0%

C14H14BrN (1632199-11-1) + tris(pentafluorophenyl)borate (1109-15-5) → C32H14BBrF15N (1632293-77-6)

Guidance literature:

In toluene; at 20 ℃; for 13h; Glovebox; Inert atmosphere;

DOI:10.1055/s-0033-1341072

upstream raw materials:

5-bromoquinoline

Downstream raw materials:

C₃₂H₁₄BBrF₁₅N

Refernces