2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene

Base Information

• Chemical Name: 2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene
• CAS No.: 1123921-73-2
• Molecular Formula: C₅₆H₃₈N₂
• Molecular Weight: 738.931
• Mol file: 1123921-73-2.mol

Synonyms:2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene

Chemical Property of 2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene

There total 8 articles about 2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

(N-phenyl)-N-(9-phenyl-9H-carbazole-3-yl)amine (894791-43-6) + 2-(3-bromophenyl)-9,10-diphenylanthracene (1123921-74-3) → 2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene (1123921-73-2)

Guidance literature:

With tri-tert-butyl phosphine; sodium t-butanolate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In hexane; toluene; at 80 ℃; for 5h; Inert atmosphere;

Reference yield:

2-bromoanthracene-9,10-dione (572-83-8) → 2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene (1123921-73-2)

Guidance literature:

Multi-step reaction with 5 steps

1.1: tetrahydrofuran / 12 h / 20 °C / Inert atmosphere

2.1: potassium iodide; acetic acid; sodium hypophosphite monohydrate / 2 h / 120 °C

2.2: 1 h / 120 °C

3.1: n-butyllithium; sodium thiosulfate / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

3.2: 13 h / -78 - 20 °C

3.3: 1 h / 20 °C

4.1: potassium carbonate; tris-(o-tolyl)phosphine / palladium diacetate / toluene; water / 8 h / 110 °C / Inert atmosphere

5.1: sodium t-butanolate; tri-tert-butyl phosphine / bis(dibenzylideneacetone)-palladium⁽⁰⁾ / toluene; hexane / 5 h / 80 °C / Inert atmosphere

With n-butyllithium; sodium hypophosphite monohydrate; tri-tert-butyl phosphine; potassium carbonate; sodium thiosulfate; acetic acid; tris-(o-tolyl)phosphine; potassium iodide; sodium t-butanolate; palladium diacetate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; hexane; water; toluene;

Reference yield:

2-aminoanthraquinone (117-79-3) → 2-{3-[N-phenyl-N-(9-phenylcarbazol-3-yl)amino]phenyl}-9,10-diphenylanthracene (1123921-73-2)

Guidance literature:

Multi-step reaction with 6 steps

1.1: copper(ll) bromide; tert.-butylnitrite / acetonitrile / 6 h / 65 °C

1.2: 3 h

2.1: tetrahydrofuran / 12 h / 20 °C / Inert atmosphere

3.1: potassium iodide; acetic acid; sodium hypophosphite monohydrate / 2 h / 120 °C

3.2: 1 h / 120 °C

4.1: n-butyllithium; sodium thiosulfate / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

4.2: 13 h / -78 - 20 °C

4.3: 1 h / 20 °C

5.1: potassium carbonate; tris-(o-tolyl)phosphine / palladium diacetate / toluene; water / 8 h / 110 °C / Inert atmosphere

6.1: sodium t-butanolate; tri-tert-butyl phosphine / bis(dibenzylideneacetone)-palladium⁽⁰⁾ / toluene; hexane / 5 h / 80 °C / Inert atmosphere

With n-butyllithium; tert.-butylnitrite; sodium hypophosphite monohydrate; tri-tert-butyl phosphine; potassium carbonate; sodium thiosulfate; acetic acid; tris-(o-tolyl)phosphine; potassium iodide; copper(ll) bromide; sodium t-butanolate; palladium diacetate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; hexane; water; toluene; acetonitrile;

upstream raw materials:

2-aminoanthraquinone

2-bromoanthracene-9,10-dione

2-bromo-9,10-diphenylanthracene

2-bromo-9,10-diphenyl-9,10-dihydro-anthracene-9,10-diol

Refernces