p-cresolate

Base Information

• Chemical Name: p-cresolate
• CAS No.: 22113-51-5
• Molecular Formula: C₇H₇O
• Molecular Weight: 107.132
• Mol file: 22113-51-5.mol

Synonyms:p-cresolate

Chemical Property of p-cresolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of p-cresolate

There total 33 articles about p-cresolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1H-imidazole (288-32-4) + 1-acetoxy-4-methylbenzene (140-39-6) → N-Acetylimidazole (2466-76-4) + p-cresolate (22113-51-5)

Guidance literature:

In water; at 20 ℃; Kinetics;

DOI:10.1002/kin.20074

Reference yield:

p-cresyl benzoate (614-34-6) → p-cresolate (22113-51-5) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With hydroxide; In water; dimethyl sulfoxide; at 25 ℃; Kinetics; Alkaline hydrolysis;

DOI:10.1021/jo026339g

Reference yield:

2-p-Tolyloxycarbonyl-benzoic acid anion → phthalic anhydride (85-44-9) + p-cresolate (22113-51-5)

Guidance literature:

In water; acetonitrile; at 25 ℃; pH=8.50; Equilibrium constant;

DOI:10.1021/jo048183l

upstream raw materials:

(2R,3S,4S,5R,6S)-2-Hydroxymethyl-6-p-tolyloxy-tetrahydro-pyran-3,4,5-triol

p-cresol

acetate

C₁₄H₁₃NO

Downstream raw materials:

p-methylphenoxyl radical

phenolate

p-methoxyphenolate

1-acetoxy-4-methylbenzene

Refernces

• 1、 Bernasconi, Claude F.,Perez-Lorenzo, Moises,Codding, Sara J.. "Reactions of [aryloxy(phenyl)carbene]pentacarbonylchromium(0) complexes with thiolate ions. Decreasing reactivity with increasing basicity of the nucleophile". . p. 9456 - 9463. Retrieved 2008/03/15.
• 2、 Rajarathnam,Jeyakumar,Nadar, P. Ananthakrishna. "Mechanistic change in the reactivity of substituted phenyl acetates over phenyl thiolacetates toward imidazole in aqueous phase". . p. 211 - 221. Retrieved 2007/10/03.