10-hydroxy-10-benzyl-9(10H)-anthracenone

Base Information

• Chemical Name: 10-hydroxy-10-benzyl-9(10H)-anthracenone
• CAS No.: 78787-97-0
• Molecular Formula: C₂₁H₁₆O₂
• Molecular Weight: 300.357
• Mol file: 78787-97-0.mol

Synonyms:10-hydroxy-10-benzyl-9(10H)-anthracenone

Chemical Property of 10-hydroxy-10-benzyl-9(10H)-anthracenone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-hydroxy-10-benzyl-9(10H)-anthracenone

There total 15 articles about 10-hydroxy-10-benzyl-9(10H)-anthracenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

9-benzylanthracene (1498-71-1) → 10-hydroxy-10-benzyl-9(10H)-anthracenone (78787-97-0)

Guidance literature:

With iron(III) perchlorate; In acetonitrile; at 24.9 ℃;

DOI:10.1246/cl.1993.1911

Reference yield: 59.0%

9,10-dihydro-9,10-dihydroxyanthracene (58343-58-1) + benzyl chloride (100-44-7) → 10-hydroxy-10-benzyl-9(10H)-anthracenone (78787-97-0)

Guidance literature:

With sodium hydroxide; In water; at 60 ℃;

DOI:10.1021/jo00340a006

Reference yield: 43.0%

9,10-phenanthrenequinone (84-65-1) + toluene (108-88-3,15644-74-3,16713-13-6) → 10-hydroxy-10-benzyl-9(10H)-anthracenone (78787-97-0)

Guidance literature:

With di-tert-butyl peroxide; for 8h; Irradiation;

DOI:10.1007/BF00955312

upstream raw materials:

9-benzylanthracene

benzyl bromide

9,10-phenanthrenequinone

benzyldimethylphenylammonium chloride

Downstream raw materials:

10-Benzyl-9,10-dihydro-[9]anthrol

benzylideneanthrone

9-benzylanthracene

Refernces

• 1、 Fujita, Morifumi,Fukuzumi, Shunichi. "Electron-Transfer Oxidation of 9-Alkylanthracenes and the Decay Kinetics of Radical Cations in Acetonitrile". . p. 1911 - 1914. Retrieved 1993.
• 2、 Bruni, Paolo,Carloni, Patricia,Conti, Carla,Giorgini, Elisabetta,Greci, Lucedio,Iacussi, Marco,Stipa, Pierluigi,Tosi, Giorgio. "Competition between nucleophilic addition and electron-transfer process in the reaction of 9-diazo-10-anthrone with Grignard reagents". . p. 6795 - 6802. Retrieved 2007/10/03.