EXO-2-CHLORONORBORNANE)

Base Information

• Chemical Name: EXO-2-CHLORONORBORNANE)
• CAS No.: 67844-27-3
• Molecular Formula: C₇H₁₁Cl
• Molecular Weight: 130.617
• Mol file: 67844-27-3.mol

Synonyms:exo-2-norbornyl chloride

Chemical Property of EXO-2-CHLORONORBORNANE)

Chemical Property:

• Vapor Pressure: 3.29mmHg at 25°C

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of EXO-2-CHLORONORBORNANE)

There total 9 articles about EXO-2-CHLORONORBORNANE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

norbornene (279-23-2) → Norbornan-2-on (497-38-1) + 7-norbornanol (2566-48-5) + exo-2-norbornanol (497-37-0) + (+/-)-endo-2-norborneol (497-36-9) + exo-2-norbornyl chloride (67844-27-3) + endo-2-norbornyl chloride (765-91-3,2999-06-6,29342-53-8,36025-11-3,67844-26-2,67844-27-3,130726-60-2)

Guidance literature:

With tetrachloromethane; ozone; at 25 ℃; Rate constant; Product distribution; Mechanism; other norbornane derivatives, var. temperatures; E_a, log A per H;

DOI:10.1021/jo00250a005

Reference yield:

norbornene (279-23-2) → Norbornan-2-on (497-38-1) + 7-norbornanol (2566-48-5) + exo-2-norbornanol (497-37-0) + (+/-)-endo-2-norborneol (497-36-9) + exo-2-norbornyl chloride (67844-27-3) + endo-2-norbornyl chloride (765-91-3,2999-06-6,29342-53-8,36025-11-3,67844-26-2,67844-27-3,130726-60-2)

Guidance literature:

With tetrachloromethane; ozone; at 25 ℃; Rate constant; Product distribution; Mechanism; other norbornane derivatives, var. temperatures; E_a, log A per H;

DOI:10.1021/jo00250a005

Reference yield:

norbornene (279-23-2) → Norbornan-2-on (497-38-1) + exo-2-norbornanol (497-37-0) + exo-2-norbornyl chloride (67844-27-3)

Guidance literature:

With nitronium tetrafluoborate; Mechanism; Product distribution; Ambient temperature; various times;

DOI:10.1021/jo00069a028

upstream raw materials:

norbornene

norborn-2-ene

Norbornan-2-on

Downstream raw materials:

exo-2-norbornanol

(1R,4S)-Bicyclo[2.2.1]heptan-2-ol

norbornene

exo-2-phenylnorbornane

Refernces

• 1、 Olah, G. A.,Ramaiah, Pichika. "Oxygenation of Bicycloheptane and Bicyclooctane with Nitronium Tetrafluoroborate". . p. 4639 - 4641. Retrieved 2007/10/02.
• 2、 Giamalva, David H.,Church, Daniel F.,Pryor, William A.. "Kinetics of Ozonation. 6. Polycyclic Aliphatic Hydrocarbons.". . p. 3429 - 3432. Retrieved 2007/10/02.