2,9-Di(cyclohexyl)-anthra2,1,9-def:6,5,10-d'e'f'diisoquinoline-1,3,8,10-tetrone

Base Information

• Chemical Name: 2,9-Di(cyclohexyl)-anthra2,1,9-def:6,5,10-d'e'f'diisoquinoline-1,3,8,10-tetrone
• CAS No.: 41572-86-5
• Molecular Formula: C36H32N2O4
• Molecular Weight: 554.645
• Mol file: 41572-86-5.mol

Synonyms:N,N'-dicyclohexyl-oxalamide;NN'-Dicyclohexyloxamide;N,N'-dicyclohexylperylene-3,4:9,10-tetracarboxylic acid bisimide;Oxamide,N,N'-dicyclohexyl;2,5-DIPHENYLBENZENE-1,4-DICARBOXYLIC ACID;N,N'-dicyclohexyl-3,4:9,10-tetracarboxylic acidbisimide;N-cyclohexyl-N'-cyclohexylethane-1,2-diamide;N,N'-Bis-cyclohexyl-oxaldiamid;N,N'-Dicyclohexyl-dioxamid;N,N'-dicyclohexylperylene-3,4:9,10-tetracarboxydiimide;N,N'-Dicyclohexyl-oxalamid;N,N'-dicyclohexylethanediamide;N,N'-dicyclohexylperylene-3,4:9,10-tetracarboxylic diimide;N.N'-Dicyclohexyl-oxamid;

Chemical Property of 2,9-Di(cyclohexyl)-anthra2,1,9-def:6,5,10-d'e'f'diisoquinoline-1,3,8,10-tetrone

Chemical Property:

• PSA: 78.14000
• LogP: 6.97340

Purity/Quality:

99% purity ^*data from raw suppliers

2,9-DI(CYCLOHEXYL)-ANTHRA[2,1,9-DEF:6,5,10- D'E'F']DIISOQUINOLINE-1,3,8,10-TETRONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,9-Di(cyclohexyl)-anthra2,1,9-def:6,5,10-d'e'f'diisoquinoline-1,3,8,10-tetrone

There total 6 articles about 2,9-Di(cyclohexyl)-anthra2,1,9-def:6,5,10-d'e'f'diisoquinoline-1,3,8,10-tetrone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

cyclohexylamine (108-91-8,157973-60-9) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide (41572-86-5)

Guidance literature:

at 135 ℃; for 24h;

Reference yield: 95.0%

N-cyclohexyl-1,8-naphthalimide (39061-31-9) → N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide (41572-86-5)

Guidance literature:

With 2,6-dichloro-benzonitrile; potassium tert-butylate; In acetonitrile; at 170 ℃;

DOI:10.1021/jo0010835

Reference yield: 91.0%

cyclohexane (110-82-7,25012-93-5) + 3,4,9,10-perylene tetracarboxyxlic acid diimide (81-33-4) → N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide (41572-86-5)

Guidance literature:

for 24h; Reflux; Inert atmosphere;

DOI:10.1039/c3tc31097c

upstream raw materials:

cyclohexylamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

N-cyclohexyl-1,8-naphthalimide

cyclohexanone-oxime

Downstream raw materials:

2,9-dicyclohexyl-5-nitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

Refernces

• 1、 Geffroy, Bernard,Hissler, Muriel,Hoffmann, Jonas,Jaques, Emmanuel,Staubitz, Anne. "Tuning the aggregation behaviour of BN-coronene diimides with imide substituents and their performance in devices (OLEDs and OFETs)". supporting information. p. 14720 - 14729. Retrieved 2021/11/09.
• 2、 He, Junjie,Li, Song,Zeng, Heping. "The Photostability of Two Optical Materials Based on Perylene Diimide Substituted by Different Aromatic Groups at the Bay Area". . p. 2800 - 2807. Retrieved 2017/09/26.