Potassium cyclohexyltrifluoroborate

Base Information

• Chemical Name: Potassium cyclohexyltrifluoroborate
• CAS No.: 446065-11-8
• Molecular Formula: C6H11 B F3 . K
• Molecular Weight: 190.058
• Mol file: 446065-11-8.mol

Synonyms:Potassium cyclohexyltrifluoroborate

Chemical Property of Potassium cyclohexyltrifluoroborate

Chemical Property:

• Melting Point: 187-192 °C
• PSA: 0.00000
• LogP: 3.16810
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Potassium cyclohexyltrifluoroborate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Potassium cyclohexyltrifluoroborate

There total 15 articles about Potassium cyclohexyltrifluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[(4R,5R)-4,5-dicyclohexyl-1-cyclohexyl]-1,3,2-dioxaborolane → cyclohexyltrifluoro-λ4-borane potassium salt (446065-11-8)

Guidance literature:

With potassium hydrogen difluoride; In methanol; water; at 22 ℃;

DOI:10.1021/ol025973d

Reference yield: 82.0%

cyclohexene (110-83-8) → cyclohexyltrifluoro-λ4-borane potassium salt (446065-11-8)

Guidance literature:

cyclohexene; With PyBH₂I; In dichloromethane; at 20 ℃;

With potassium hydrogen bifluoride; In methanol; at 20 ℃;

DOI:10.1021/ja043743j

Reference yield: 82.0%

potassium hydrogenfluoride (1279123-63-5) + borane pyridine (110-51-0) + cyclohexene (110-83-8) → cyclohexyltrifluoro-λ4-borane potassium salt (446065-11-8)

Guidance literature:

With iodine; In methanol; dichloromethane; to soln. of CHCHC4H8 in CH2Cl2 added PyBH3 and I2; then soln. of KHF2 inMeOH added; MS, NMR;

DOI:10.1021/ja043743j

upstream raw materials:

cyclohexene

potassium hydrogenfluoride

borane pyridine

cyclohexylmagnesiumchloride

Downstream raw materials:

3-cyclohexylpyridine

2-cyclohexylanisole

N-cyclohexylacetamide

1-cyclohexyl-3-phenyl-1-propanone

Refernces

• 1、 Amos, Stephanie G. E.,Cavalli, Diana,Le Vaillant, Franck,Waser, Jerome. "Direct Photoexcitation of Ethynylbenziodoxolones: An Alternative to Photocatalysis for Alkynylation Reactions**". supporting information. p. 23827 - 23834. Retrieved 2021/09/25.
• 2、 Zillman, David J.,Cole, Thomas E.. "Preparation of alkyltrifluoroborates via Matteson Hydroboration Method". . p. 159 - 165. Retrieved 2018/04/05.