2-Bromovinyltrimethylsilane

Base Information Edit

Chemical Name:2-Bromovinyltrimethylsilane
CAS No.:41309-43-7
Molecular Formula:C5H11BrSi
Molecular Weight:179.132
Hs Code.:2931900090
European Community (EC) Number:628-813-1
Nikkaji Number:J1.239.390C,J428.906D
Wikidata:Q76305672
Mol file:41309-43-7.mol

Synonyms:41309-43-7;2-BROMOVINYLTRIMETHYLSILANE;2-(Bromovinyl)trimethylsilane;(E)-(2-bromovinyl)trimethylsilane;(E)-(2-Bromoethenyl)trimethylsilane;(2-Bromovinyl)trimethylsilane;[(E)-2-bromoethenyl]-trimethylsilane;trans-1-bromo-2-(trimethylsilyl)ethene;Silane, (2-bromoethenyl)trimethyl-;(2-Bromovinyl)trimethylsilane, approx. 90% trans, 98%;MFCD00040824;1-Bromo-2-(trimethylsilyl)ethylene;[(E)-2-Bromovinyl](trimethyl)silane;Silane, [(1E)-2-bromoethenyl]trimethyl-;1(bromovinyl)trimethylsilane;1-(Bromovinyl)trimethylsilane;SCHEMBL503069;(2-Bromoethenyl)trimethyl-silane;AMY1268;FKXCNOSKBLGEMQ-SNAWJCMRSA-N;beta-(Trimethylsilyl)vinyl bromide;trans(2-Bromovinyl)trimethylsilane;[(E)-2-bromoethenyl]trimethylsilane;Trimethyl[(E)-2-bromoethenyl]silane;AKOS015913382;AS-30116;AS-80238;[(E)-2-Bromoethenyl](trimethyl)silane #;S03150;(2-Bromovinyl)trimethylsilane, approx. 90% trans;J-500661;J-802001;(2-Bromovinyl)trimethylsilane, purum, ~87% (trans + ~13% cis)

Suppliers and Price of 2-Bromovinyltrimethylsilane

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(2-Bromovinyl)trimethylsilane approx. 90% trans, 98%
5ml
$ 208.00

Arctom
(E)-(2-Bromovinyl)trimethylsilane
25g
$ 295.00

Total 60 raw suppliers

Chemical Property of 2-Bromovinyltrimethylsilane Edit

Chemical Property:

Refractive Index:n20/D 1.466(lit.)
Boiling Point:125.7 °C at 760 mmHg
Flash Point:29.4 °C
PSA：0.00000
Density:1.166 g/cm³
LogP:2.77240
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:177.98134
Heavy Atom Count:7
Complexity:70.6

Purity/Quality:

98%, ^*data from raw suppliers

(2-Bromovinyl)trimethylsilane approx. 90% trans, 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 10-36/37/38
Safety Statements: 26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C=CBr
Isomeric SMILES:C[Si](C)(C)/C=C/Br

Technology Process of 2-Bromovinyltrimethylsilane

There total 8 articles about 2-Bromovinyltrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1066-54-2
trimethylsilylacetylene

: 41309-43-7
(2-bromovinyl)trimethylsilane

Guidance literature:: With hydrogen bromide; dibenzoyl peroxide; Inert atmosphere; Cooling with ice;
DOI:10.1021/jo900922q

Reference yield: 63.0%

: 1066-54-2
trimethylsilylacetylene

: 41309-43-7,70737-20-1,13682-94-5
(2-bromovinyl)trimethylsilane

Guidance literature:: With hydrogen bromide; dibenzoyl peroxide;
DOI:10.1002/jccs.200400126

Reference yield:

: 18178-59-1
(E)-1,2-bis(trimethylsilyl)ethene

: 41309-43-7
(2-bromovinyl)trimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: Br₂ / CH₂Cl₂

2: KF / dimethylsulfoxide / 1 h / Ambient temperature

3: 16 h / 180 °C

With potassium fluoride; bromine; In dichloromethane; dimethyl sulfoxide;