Technology Process of (R)-butyl(2-(1-methoxyethyl)phenyl)tellane
There total 5 articles about (R)-butyl(2-(1-methoxyethyl)phenyl)tellane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
1-(2-(butyltellanyl)phenyl)ethanol;
With
sodium hydride;
In
tetrahydrofuran;
at 0 ℃;
for 0.5h;
methyl iodide;
at 20 ℃;
for 2h;
optical yield given as %ee;
DOI:10.1039/c0ob01050b
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / pentane / 24 h / Reflux
1.2: 0 - 20 °C
2.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 °C
2.2: 2 h / 20 °C
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine; sodium hydride;
In
tetrahydrofuran; pentane;
DOI:10.1039/c0ob01050b
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: Candida antartica lipase-B / hexane / 7 h / 32 °C / Enzymatic reaction
2.1: water; potassium carbonate / methanol / 20 °C
3.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / pentane / 24 h / Reflux
3.2: 0 - 20 °C
4.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 °C
4.2: 2 h / 20 °C
With
n-butyllithium; N,N,N,N,-tetramethylethylenediamine; Candida antartica lipase-B; water; sodium hydride; potassium carbonate;
In
tetrahydrofuran; methanol; hexane; pentane;
DOI:10.1039/c0ob01050b
