N,N-di-n-butyl-2,4-dinitroaniline

Base Information

• Chemical Name: N,N-di-n-butyl-2,4-dinitroaniline
• CAS No.: 75113-69-8
• Molecular Formula: C₁₄H₂₁N₃O₄
• Molecular Weight: 295.338
• Mol file: 75113-69-8.mol

Synonyms:N,N-di-n-butyl-2,4-dinitroaniline

Chemical Property of N,N-di-n-butyl-2,4-dinitroaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-di-n-butyl-2,4-dinitroaniline

There total 9 articles about N,N-di-n-butyl-2,4-dinitroaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) + dibutylamine (111-92-2) → N,N-di-n-butyl-2,4-dinitroaniline (75113-69-8)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; for 3h; Heating;

DOI:10.1071/CH9950997

Reference yield: 68.0%

tributyl-amine (102-82-9) + 2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) → N,N-di-n-butyl-2,4-dinitroaniline (75113-69-8)

Guidance literature:

With tris[2-phenylpyridinato-C₂,N]iridium(III); N-ethyl-N,N-diisopropylamine; In dimethyl sulfoxide; at 20 ℃; for 40h; Irradiation;

DOI:10.3390/molecules26113323

Reference yield: 53.0%

N-Dibutylaniline (613-29-6) → N,N-di-n-butyl-2,4-dinitroaniline (75113-69-8) + N,N-di-n-butyl-2-nitroaniline

Guidance literature:

With sulfuric acid; sodium nitrite; In water; at 50 ℃; for 0.5h; Solvent;

DOI:10.1039/d1nj05084b

upstream raw materials:

2,4-Dinitrofluorobenzene

dibutylamine

1-chloro-2,4-dinitro-benzene

2,4-dinitrobromobenzene

Refernces

• 1、 Amosov, Evgeny,Bagryanskaya, Irina,Karpova, Elena,Selivanova, Galina,Shundrina, Inna,Skolyapova, Alexandrina,Wang, Jiaying. "Azo dyes containing 1,3,4-thiadiazole fragment: Synthesis and properties". supporting information. p. 1929 - 1942. Retrieved 2022/01/31.
• 2、 Gale, Douglas J.,Rosevear, Judi,Wilshire, John F. K.. "The Anomalous Reactions of Some Fluoronitrobenzenes with Some N,N-Dialkylamines". . p. 997 - 1008. Retrieved 2007/10/02.