1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose

Base Information

• Chemical Name: 1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose
• CAS No.: 67831-76-9
• Molecular Formula: C₁₂H₁₆O₈
• Molecular Weight: 288.254
• Mol file: 67831-76-9.mol

Synonyms:1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose

Chemical Property of 1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose

There total 1 articles about 1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetic anhydride (108-24-7) + Sucrose (57-50-1) → 1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose (67831-76-9) + ((2R,3S,4S,5R)-3,4,5,6-tetrahydroxytetrahydro-2H-pyran-2-yl)methyl acetate (118759-70-9) + sucrose octaacetate (126-14-7)

Guidance literature:

With triethylboraxine; Yield given. Multistep reaction. Yields of byproduct given; 1.) pyridine, toluene, 130 deg C (bath temp.), 22 h, 2.) 30 deg C, 8 h;

DOI:10.1055/s-1983-30618

Reference yield: 88.0%

1,3,4-Tri-O-acetyl-2,6-anhydro-β-D-fructofuranose (67831-76-9) → 2,6-Anhydro-β-D-fructofuranose (38982-46-6)

Guidance literature:

With sodium methylate; In methanol; for 0.5h; Ambient temperature;

DOI:10.1055/s-1983-30618

upstream raw materials:

acetic anhydride

Sucrose

Downstream raw materials:

2,6-Anhydro-β-D-fructofuranose

Refernces