1-(naphthyl-⁽²⁾)-ethanone-⁽¹⁾-seqtrans-oxime

Base Information

• Chemical Name: 1-(naphthyl-⁽²⁾)-ethanone-⁽¹⁾-seqtrans-oxime
• CAS No.: 100485-52-7
• Molecular Formula: C₁₂H₁₁NO
• Molecular Weight: 185.225
• Mol file: 100485-52-7.mol

Synonyms:1-(naphthyl-⁽²⁾)-ethanone-⁽¹⁾-seqtrans-oxime

Chemical Property of 1-(naphthyl-⁽²⁾)-ethanone-⁽¹⁾-seqtrans-oxime

Chemical Property:

Purity/Quality:

1-(2-naphthyl)ethanoneoxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-(naphthyl-⁽²⁾)-ethanone-⁽¹⁾-seqtrans-oxime

There total 8 articles about 1-(naphthyl-⁽²⁾)-ethanone-⁽¹⁾-seqtrans-oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methyl 2-naphthyl ketone (93-08-3) → 2-acetonaphthone oxime (100485-52-7,100485-60-7,51674-06-7)

Guidance literature:

With hydroxylamine hydrochloride;

DOI:10.1021/jo902259u

Reference yield: 100.0%

→ 2-acetonaphthone oxime (100485-52-7,100485-60-7,51674-06-7)

Guidance literature:

Reference yield: 99.0%

methyl 2-naphthyl ketone (93-08-3) → 1-(naphthyl-(2))-ethanone-(1)-seqtrans-oxime (100485-52-7)

Guidance literature:

With ethyl acetohydroximate; scandium tris(trifluoromethanesulfonate); In ethanol; at 20 ℃; for 24h; Reagent/catalyst; Solvent; Temperature; stereoselective reaction; Catalytic behavior; Inert atmosphere;

upstream raw materials:

pyridine

ethanol

methyl 2-naphthyl ketone

1,4-dioxane

Downstream raw materials:

1-(2-Naphthyl)ethylamine

N-hydroxy-1-(2-naphthyl)ethylamine

N-Phenyl-N'-<2-(2-naphthyl)-ethyl>-harnstoff

N-Phenyl-N'-<2-hydroxy-2-(β-naphthyl)-ethyl>-harnstoff

Refernces

• 1、 Smith. "-". . . Retrieved 1954.
• 2、 Terentev, Alexander O.,Krylov, Igor B.,Vil, Vera A.,Pastukhova, Zhanna Yu.,Fastov, Sergey A.,Nikishin, Gennady I.. "Synthesis of dibromo ketones by the reaction of the environmentally benign H2O2-HBr system with oximes". . p. 360 - 367. Retrieved 2012.
• 3、 Markova,Morozova,Tatarinova,Mikhaleva,Hyun, Sang Heon,Shmidt,Zorina,Myachina,Trofimov. "Selective synthesis and radical polymerization of N-vinyl-2-(1-naphthyl)- and N-vinyl-2-(2-naphthyl)pyrroles". . p. 219 - 222. Retrieved 2010.
• 4、 Tang, Wenjun,Capacci, Andrew,Sarvestani, Max,Wei, Xudong,Yee, Nathan K.,Senanayake, Chris H.. "A facile and practical synthesis of N-acetyl enamides". . p. 9528 - 9530. Retrieved 2009.
• 5、 Wang, Quannan,Lou, Jiang,Huang, Zilong,Yu, Zhengkun. "Rhodium(III)-Catalyzed Annulation of Acetophenone O-Acetyl Oximes with Allenoates through Arene C-H Activation: An Access to Isoquinolines". . p. 2083 - 2092. Retrieved 2019.
• 6、 Liu, Yinghui,Wei, Yongjiao,Xie, Lan-Gui. "Dehydrative Beckmann rearrangement and the following cascade reactions". supporting information. . Retrieved 2021/11/16.
• 7、 Tang, Kai,Chen, Yixuan,Guan, Jianping,Wang, Zhujun,Chen, Kai,Xiang, Haoyue,Yang, Hua. "Visible-light-promoted olefinic trifluoromethylation of enamides with CF3SO2Na". supporting information. p. 7475 - 7479. Retrieved 2021/09/08.