bis(2-phenethyl)vinylphosphine sulfide

Base Information

• Chemical Name: bis(2-phenethyl)vinylphosphine sulfide
• CAS No.: 1202745-32-1
• Molecular Formula: C₁₈H₂₁PS
• Molecular Weight: 300.404
• Mol file: 1202745-32-1.mol

Synonyms:bis(2-phenethyl)vinylphosphine sulfide

Chemical Property of bis(2-phenethyl)vinylphosphine sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(2-phenethyl)vinylphosphine sulfide

There total 3 articles about bis(2-phenethyl)vinylphosphine sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

divinyltellane (63000-06-6) + bis(2-phenylethyl)phosphane sulfide → bis(2-phenethyl)vinylphosphine sulfide (1202745-32-1)

Guidance literature:

In neat (no solvent); at 80 - 82 ℃; for 125h; Inert atmosphere; Green chemistry;

DOI:10.1080/17415993.2016.1191635

Reference yield:

[2-(ethylsulfinyl)ethyl]bis(2-phenylethyl)phosphane sulfide → bis(2-phenethyl)vinylphosphine sulfide (1202745-32-1)

Guidance literature:

With potassium hydroxide; In 1,4-dioxane; at 40 - 70 ℃;

DOI:10.1002/mrc.2386

Reference yield:

bis(2-phenylethyl)[2-(phenylsulfinyl)ethyl]phosphane sulfide → bis(2-phenethyl)vinylphosphine sulfide (1202745-32-1)

Guidance literature:

With potassium hydroxide semihydrate; In 1,4-dioxane; at 70 ℃; for 1.5h; Inert atmosphere;

DOI:10.1080/10426500903329245

upstream raw materials:

divinyltellane

Downstream raw materials:

bis(2-phenethyl)vinylphosphine

Refernces

• 1、 Gusarova, Nina K.,Chernysheva, Nataliya A.,Yas’ko, Svetlana V.,Klyba, Lyudmila V.,Trofimov, Boris A.. "Non-catalyzed addition of secondary phosphine chalcogenides to divinyl chalcogenides under solvent-free conditions". . p. 488 - 500. Retrieved 2016/10/03.