niobocene trihydride

Base Information

• Chemical Name: niobocene trihydride
• CAS No.: 11105-67-2
• Molecular Formula: C₁₀H₁₃Nb
• Molecular Weight: 226.12
• Mol file: 11105-67-2.mol

Synonyms:niobocene trihydride

Chemical Property of niobocene trihydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of niobocene trihydride

There total 1 articles about niobocene trihydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

endo-(cyclopentadienyl)2Nb(H2BO2C6H3C(CH3)3) + hydrogen (1333-74-0) → niobocene trihydride (11105-67-2) + borane (13283-31-3)

Guidance literature:

In benzene-d6; (inert atm.); Nb compd. soln. placed in NMR tube, freezing (liq. N2), evacuation, H2 addn.; not isolated; monitored by NMR;

DOI:10.1021/ja970639b

Reference yield: 100.0%

niobocene trihydride (11105-67-2) + diazodiphenylmethane (908093-98-1) → Cp2Nb(H)(η(1)-NNCPh2)

Guidance literature:

byproducts: H2; NMR;

DOI:10.1016/0022-328X(93)83233-L

Reference yield: 90.0%

niobocene trihydride (11105-67-2) + benzene-d6 (1076-43-3) → hydrogen (1333-74-0) + deuterium hydride + deuterium (16873-17-9,12184-84-8)

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); irradn. with 450-W Hanovia lamp for 36 h at 15°C (Ar); not isolated, detected by MS;

DOI:10.1021/ja00385a015

upstream raw materials:

hydrogen

Downstream raw materials:

niobocene dichloride

hydrogen

deuterium

(C₅H₅)2Nb(P(C(CH₃)3)2)Cl

Refernces