p-nitrobenzyl methyl carbonate

Base Information

• Chemical Name: p-nitrobenzyl methyl carbonate
• CAS No.: 99107-22-9
• Molecular Formula: C₉H₉NO₅
• Molecular Weight: 211.174
• Mol file: 99107-22-9.mol

Synonyms:p-nitrobenzyl methyl carbonate

Chemical Property of p-nitrobenzyl methyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-nitrobenzyl methyl carbonate

There total 3 articles about p-nitrobenzyl methyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-nitrobenzyl chloride (619-73-8) + carbonic acid dimethyl ester (616-38-6) → p-nitrobenzyl methyl carbonate (99107-22-9)

Guidance literature:

With 3-methyl-1-(trimethoxysilylpropyl)imidazolium chloride; at 80 ℃; for 6.5h; Inert atmosphere;

DOI:10.1039/c3nj00640a

Reference yield: 19.0%

2-methoxy-5,5-dimethyl-2-(4-nitro-benzyloxy)-2,5-dihydro-[1,3,4]oxadiazole → methyl (4-nitrophenyl)acetate (2945-08-6) + p-nitrobenzyl methyl carbonate (99107-22-9) + C16H16N2O7

Guidance literature:

In benzene; at 100 ℃; for 96h; Kinetics; Thermolysis;

DOI:10.1139/v00-021

Reference yield:

methanol (67-56-1) + 4-nitrobenzyl chloroformate (4457-32-3) → p-nitrobenzyl methyl carbonate (99107-22-9)

Guidance literature:

DOI:10.1021/ja01100a053

upstream raw materials:

methanol

4-nitrobenzyl chloroformate

4-nitrobenzyl chloride

carbonic acid dimethyl ester

Downstream raw materials:

4-benzyl-1-nitrobenzene

4-nitrobenzyl chloride

Refernces

• 1、 Bi, Xiuru,Yao, Nan,Meng, Xu,Gou, Mingxia,Zhao, Peiqing. "MnCO3-Catalyzed Transesterification of Alcohols with Dimethyl Carbonate Under Mild Conditions". . p. 454 - 462. Retrieved 2020/07/16.