Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂

Base Information

• Chemical Name: Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂
• CAS No.: 848652-20-0
• Molecular Formula: C₅₂H₇₀Cl₂O₄P₂Pd
• Molecular Weight: 998.399
• Mol file: 848652-20-0.mol

Synonyms:Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂

Chemical Property of Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂

There total 1 articles about Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane (657408-07-6) + dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4) → Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)2Cl2 (848652-20-0)

Guidance literature:

In dichloromethane; mixt. ligand and (CH3CN)2PdCl2 in CH2Cl2 was stirred; flash chromy. on silica;

DOI:10.1021/ja042491j

Reference yield:

silver tetrafluoroborate (14104-20-2) + Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)2Cl2 (848652-20-0) + acetone (67-64-1) → ((CH3O)2C6H3C6H4P(C6H11)2Pd)2(2+)*2BF4(1-)*CH3COCH3=((CH3O)2C6H3C6H4P(C6H11)2Pd)2(BF4)2*CH3COCH3

Guidance literature:

In dichloromethane; under Ar atm. mixt. Pd complex and AgBF4 in CH2Cl2 at ambient temp. was stirred for 3 h; product was recrystd. from acetone/Et2O at -25°C;

DOI:10.1021/ja0558995

upstream raw materials:

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

dichloro bis(acetonitrile) palladium(II)

Refernces