oxime of 1,5-anhydro-D-fructose

Base Information

• Chemical Name: oxime of 1,5-anhydro-D-fructose
• CAS No.: 75414-31-2
• Molecular Formula: C₆H₁₁NO₅
• Molecular Weight: 177.157
• Mol file: 75414-31-2.mol

Synonyms:oxime of 1,5-anhydro-D-fructose

Chemical Property of oxime of 1,5-anhydro-D-fructose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of oxime of 1,5-anhydro-D-fructose

There total 1 articles about oxime of 1,5-anhydro-D-fructose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

1,5-D-anhydrofructose (75414-43-6) → oxime of 1,5-anhydro-D-fructose (75414-31-2)

Guidance literature:

With hydroxylamine; In ethanol; at 20 ℃;

DOI:10.1080/07328300008544112

Reference yield: 60.0%

oxime of 1,5-anhydro-D-fructose (75414-31-2) → 1,5-D-anhydrofructose (75414-43-6)

Guidance literature:

With hydrogenchloride; acetaldehyde; In acetonitrile; at 25 ℃; for 8h;

DOI:10.1016/S0040-4039(00)92737-0

Reference yield:

oxime of 1,5-anhydro-D-fructose (75414-31-2) → 1,5-anhydro-D-glucitol (154-58-5,53319-04-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 60 percent / acetaldehyde/hydrochloric acid / acetonitrile / 8 h / 25 °C

2: sodium borohydride

With hydrogenchloride; sodium tetrahydroborate; acetaldehyde; In acetonitrile;

DOI:10.1016/S0040-4039(00)92737-0

upstream raw materials:

1,5-D-anhydrofructose

Downstream raw materials:

1,5-D-anhydrofructose

1,5-anhydro-D-mannitol

1,5-anhydro-D-glucitol

Refernces